Access to functionalised silver(I) and gold(I) N-heterocyclic carbenes by [2+3] dipolar cycloadditions. - Archive ouverte HAL
Article Dans Une Revue Dalton Transactions Année : 2012

Access to functionalised silver(I) and gold(I) N-heterocyclic carbenes by [2+3] dipolar cycloadditions.

Résumé

new strategy was developed for the modification of silver(I) and gold(I) N-heterocyclic carbenes. Azido groups were grafted and used either by copper-catalysed azide-alkyne cycloaddition before metallation or by thermal and "strain-promoted" 1,3-dipolar cycloaddition after metallation to functionalise the metal-NHCs.

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https://hal.science/hal-00711788

Soumis le : lundi 25 juin 2012-16:34:42

Dernière modification le : jeudi 25 avril 2024-10:08:15

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Dates et versions

hal-00711788 , version 1 (25-06-2012)

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  • HAL Id : hal-00711788 , version 1

Citer

Audrey Hospital, Clémentine Gibard, Christelle Gaulier, Lionel Nauton, Vincent Thery, et al.. Access to functionalised silver(I) and gold(I) N-heterocyclic carbenes by [2+3] dipolar cycloadditions.. Dalton Transactions, 2012, 41, pp.6803-6812. ⟨hal-00711788⟩

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