Radiative transition probabilities in the X2Πg state of CO2+ - Archive ouverte HAL
Article Dans Une Revue Journal of Quantitative Spectroscopy and Radiative Transfer Année : 2008

Radiative transition probabilities in the X2Πg state of CO2+

Céline Léonard
W. C. Maguire
  • Fonction : Auteur

Résumé

Using ab initio calculated potential energy and electric dipole moment functions, absolute radiative transition probabilities between the rovibronic Renner-Teller states of the electronic ground state X-2 Pi(g) of CO2+ have been evaluated. The rovibronic eigenstates were obtained (up to 6500 cm(-1) and J <= 13/2) from variational calculations including the Renner-Teller and spin-orbit angular momentum couplings. The absolute intensities for the rovibrational states of the neutral CO2 electronic ground state, calculated by a similar approach, are found to be in excellent agreement with experimental data. For CO2+ the presented results are expected to have similar accuracy. It is found that the overtone intensities of the antisymmetric stretching mode of CO2+ are of similar magnitude as the fundamental transitions, in contrast with CO2. The theoretically generated IR-emission spectrum is compared with the limb spectrum of the Mars atmosphere, measured by the Thermal Emission Spectrometer on Mars Global Surveyor. (C) 2007 Elsevier Ltd. All rights reserved.

Dates et versions

hal-00693582 , version 1 (02-05-2012)

Identifiants

Citer

Céline Léonard, M. Diehr, P. Rosmus, W. C. Maguire. Radiative transition probabilities in the X2Πg state of CO2+. Journal of Quantitative Spectroscopy and Radiative Transfer, 2008, 109 (4), pp.535-548. ⟨10.1016/j.jqsrt.2007.07.011⟩. ⟨hal-00693582⟩
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