The goal of this paper was to develop a modified photo-Fenton treatment able to degrade micro pollutants in municipal wastewater treatment plant (MWTP) effluents at a neutral pH with minimal iron and H2O2 concentrations. Complexation of Fe by ethylenediamine-N,N′-disuccinic acid (EDDS) leads to stabilization and solubilization of Fe at natural pH. Photo-Fenton experiments were performed in a pilot compound parabolic collector (CPC) solar plant. Samples were treated with solid phase extraction (SPE) and analyzed by HPLC-Qtrap-MS. The rapid degradation of contaminants within the first minutes of illumination and the low detrimental impact on degradation of bicarbonates present in the water suggested that radical species other than HO* are responsible for the efficiency of such photo-Fenton process. Disinfection of MWTP effluents by the same process showed promising results, although disinfection was not complete.