Comparison between experimental and theoretical estimations of the thermal expansion, concentration expansion coefficients, and viscosity for binary mixtures under pressures up to 20 MPa
Résumé
In this work, we have measured the densities of binary mixtures of n-dodecane, 1-phenyl-2-methylpropane, and 1,2,3,4-tetrahydronaphthalene for pressures varying from (0.1 to 20) MPa at an average temperature of 25 °C. By a derivative method, we have determined the thermal expansion and concentration expansion coefficients for binary mixtures of equal mass fraction. In addition, viscosities have been measured and compared with theoretical estimates. To accurately predict the thermal expansion and concentration expansion coefficients, the densities of the binary mixtures were calculated using PC-SAFT, Peng-Robinson, and volume translated Peng-Robinson equations of state. The comparison with measured densities showed that PCSAFT has a better agreement with experimental data than the other equations of state. From calculated densities we evaluated the thermal expansion and concentration expansion variation coefficients. We have found that PC-SAFT gives a suitable prediction for the two derivative properties unlike the two other equations of state. The combination of the model of Lohrenz-Bray-Clark for the viscosity of liquid mixtures and the densities calculated with the three equations of state gave a poor prediction of the viscosities of the binary mixtures.
Mots clés
Average temperature
Derivative method
Expansion coefficients
Experimental data
Mass fraction
N-dodecane
PC-SAFT
Peng-Robinson
Peng-robinson equations of state
Tetrahydronaphthalene
Theoretical estimation
Variation coefficient Engineering controlled terms: Butane
Concentration (process)
Equations of state of liquids
Naphthalene
Synthetic apertures
Thermal expansion
Thermal stress
Viscometers
Viscosity Engineering main heading: Binary mixtures