Paramagnetic dithiolene complexes as metallo-ligands: ether/thioether coordination.
Résumé
The secondary coordination ability of a paramagnetic nickel dithiolene complex, bearing an ether coordinating function within a nine-membered flexible ring, has been demonstrated in its [NiCl(DMF)(2)](+) complex, through coordination by both ether and thioether functions, allowing for a ferromagnetic interaction between both paramagnetic entities.
Domaines
Chimie organique
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