This volume contains the proceedings of the 18th International Workshop on Expressiveness in Concurrency (EXPRESS 2011), which took place on 5th September 2011 in Aachen, as a satellite workshop of CONCUR 2011. The EXPRESS workshop series aim at bringing together researchers who are interested in the expressiveness and comparison of formal models that broadly relate to concurrency. In particular, this also includes emergent fields such as logic and interaction, game-theoretic models, and service-oriented computing