A [Mn18Dy] SMM resulting from the targeted replacement of the central MnII in the S = 83/2 [Mn19]-aggregate with Dy III - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2009

A [Mn18Dy] SMM resulting from the targeted replacement of the central MnII in the S = 83/2 [Mn19]-aggregate with Dy III

Résumé

Anisotropy can be introduced into the [Mn19]-aggregate, which currently has the highest known spin ground state of S = 83/2, by the targeted replacement of the central Mn II cation with Dy III leading to a [Mn18Dy] complex with the same core topology showing slow relaxation of the magnetisation

Domaines

Matériaux

Dates et versions

hal-00625416 , version 1 (10-06-2021)

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Citer

Ayuk M. Ako, Valeriu Mereacre, Rodolphe Clérac, Wolfgang Wernsdorfer, Ian J. Hewitt, et al.. A [Mn18Dy] SMM resulting from the targeted replacement of the central MnII in the S = 83/2 [Mn19]-aggregate with Dy III. Chemical Communications, 2009, 5, pp.544-546. ⟨10.1039/b814614d⟩. ⟨hal-00625416⟩

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