Generalized Kubo relations and conditions for anomalous diffusion: Physical insights from a mathematical theorem - Archive ouverte HAL
Article Dans Une Revue The Journal of Chemical Physics Année : 2011

Generalized Kubo relations and conditions for anomalous diffusion: Physical insights from a mathematical theorem

Résumé

The paper describes an approach to anomalous diffusion within the framework of the generalized Langevin equation. Using a Tauberian theorem for Laplace transforms due to Hardy, Littlewood, and Karamata, generalized Kubo relations for the relevant transport coefficients are derived from the asymptotic form of the mean square displacement. In a second step conditions for anomalous diffusion are derived for the asymptotic forms of the velocity autocorrelation function and the associated memory function. Both spatially unconfined and confined diffusion processes are considered. The results are illustrated with semi-analytical examples.
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Dates et versions

hal-00614940 , version 1 (17-08-2011)

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Citer

Gerald R. Kneller. Generalized Kubo relations and conditions for anomalous diffusion: Physical insights from a mathematical theorem. The Journal of Chemical Physics, 2011, 134 (22), pp.Article Number: 224106. ⟨10.1063/1.3598483⟩. ⟨hal-00614940⟩
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