Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of the American Chemical Society Année : 2011

Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations

Jihyun Y. An
  • Fonction : Auteur
Chad M. Shade
  • Fonction : Auteur
Demetra A. Chengelis-Czegan
  • Fonction : Auteur
Nathaniel L. Rosi
  • Fonction : Auteur

Résumé

Luminescent metal-organic frameworks (MOFs), Ln(3+)@bio-MOF-1, were synthesized via post-synthetic cation exchange of bio-MOF-1 with Tb3+, Sm3+, Eu3+, or Yb3+, and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution.

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Chimie
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Dates et versions

hal-00608199 , version 1 (12-07-2011)

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Citer

Jihyun Y. An, Chad M. Shade, Demetra A. Chengelis-Czegan, Stéphane Petoud, Nathaniel L. Rosi. Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations. Journal of the American Chemical Society, 2011, 133 (5), pp.1220-1223. ⟨10.1021/ja109103t⟩. ⟨hal-00608199⟩
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