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Article Dans Une Revue Organic Letters Année : 2011

Facile Synthesis of Highly Fluorescent Boranil Complexes.

Denis Frath
Sébastien Azizi
  • Fonction : Auteur
Gilles Ulrich
Raymond Ziessel
  • Fonction : Auteur

Résumé

Complexation of a large variety of Anils (aniline-imines) with boron(III) precursors provides stable Boranils, some of which have been structurally characterized. Analysis of their optical properties reveals that the fluorescence stems from an intraligand charge transfer (ILCT) state with the best quantum yields reaching 90%. Chemistry on the Boranils allows grafting of photoactive modules acting as energy antennae for borondipyrromethene (Bodipy) and subphtalocyanine (SubPc) fluorophores.

Domaines

Chimie organique
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Dates et versions

hal-00606477 , version 1 (06-07-2011)

Identifiants

Citer

Denis Frath, Sébastien Azizi, Gilles Ulrich, Pascal Retailleau, Raymond Ziessel. Facile Synthesis of Highly Fluorescent Boranil Complexes.. Organic Letters, 2011, 13 (13), pp.3414-3417. ⟨10.1021/ol2011665⟩. ⟨hal-00606477⟩
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