Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2011

Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands

Résumé

The first Group 4 alkoxyimido compounds are reported. The Ti=N-OtBu group in Ti(N2NMe)(NOtBu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events.
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hal-00586606 , version 1 (18-04-2011)

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Andrew D. Schwarz, Ainara Nova-Flores, Eric Clot, Philip Mountford. Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. Chemical Communications, 2011, 47, pp.4926-4928. ⟨10.1039/c1cc10862j⟩. ⟨hal-00586606⟩
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