Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands
Résumé
The first Group 4 alkoxyimido compounds are reported. The Ti=N-OtBu group in Ti(N2NMe)(NOtBu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events.