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Article Dans Une Revue Organic Letters Année : 2010

12-Helix folding of cyclobutane beta-amino acid oligomers

Résumé

The hexamer and octamer of trans-2-aminocyclobutane carboxylic acid were prepared and their conformational preferences studied experimentally and using molecular modeling. All observations suggest a marked preference for the folding of these oligomers into a well-defined 12-helical conformation, in both solution and the solid state.

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Dates et versions

hal-00530671 , version 1 (29-10-2010)

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Carlos Fernandes, Sophie Faure, Elisabeth Pereira, Vincent Thery, Valérie Declerck, et al.. 12-Helix folding of cyclobutane beta-amino acid oligomers. Organic Letters, 2010, 12, pp.3606-3609. ⟨10.1021/ol101267u⟩. ⟨hal-00530671⟩
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