Redetermination of Mn1.44Mo8O11 : evidence of pairwise distortion of octahedral. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Acta Crystallographica Section C : Structural Chemistry [2014-...] Année : 2006

Redetermination of Mn1.44Mo8O11 : evidence of pairwise distortion of octahedral.

Résumé

Redetermination of the structure of manganese octamolybdenum undecaoxide, Mn1.44Mo8O11, revealed a doubling of the unit cell. The structure consists of infinite chains of trans-edge-sharing Mo6 octahedra cross-linked through O atoms to delimit tunnels in which the disordered Mn2+ cations reside. In comparison with the previous refinement [Carlson et al. (1989). J. Less Common Met. 156, 325-339], the metallic chains exhibit a pairwise distortion, as expected from theoretical calculations.
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hal-00525432 , version 1 (11-10-2010)

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  • HAL Id : hal-00525432 , version 1

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Philippe Gall, Patrick Gougeon. Redetermination of Mn1.44Mo8O11 : evidence of pairwise distortion of octahedral.. Acta Crystallographica Section C : Structural Chemistry [2014-..], 2006, C62, pp.i155-i157. ⟨hal-00525432⟩
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