A new 3-D La(lll)-Cu(ll) Containing Coordination Polymer with High Potential Porosity. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Inorganic Chemistry Année : 2006

A new 3-D La(lll)-Cu(ll) Containing Coordination Polymer with High Potential Porosity.

Résumé

A new 3-D coordination polymer containing both 3d and 4f ions has been designed. Its chemical formula is La2[Cu(pba)]3(H2O)8•8H2O. It crystallizes in the quadratic system, space group I41/a with a = 42.4947(9) Å, c = 16.3378(3) Å, and Z = 16. Its crystal structure can be described as a 3-D molecular framework exhibiting a complex network of interconnected zigzaglike channels. Once crystallization water molecules are removed, this compound presents a high potential porosity and a low density. The porosity has been evaluated using Connolly's algorithm.

Dates et versions

hal-00525429 , version 1 (11-10-2010)

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Carole Daiguebonne, Olivier Guillou, Nicolas Kerbellec, Magatte Camara. A new 3-D La(lll)-Cu(ll) Containing Coordination Polymer with High Potential Porosity.. Inorganic Chemistry, 2006, 45 (21), pp.8468-8470. ⟨10.1021/ic0607538⟩. ⟨hal-00525429⟩
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