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Article Dans Une Revue Tetrahedron Letters Année : 2010

Ring closing metathesis reaction in glycerol under microwave activation

Résumé

Glycerol, a biodegradable and virtually non-toxic bio-sourced chemical can be used as an alternative, reusable, sustainable solvent, with so far limited application in the field of green organic chemistry. Herein, reaction conditions have been screened for the ring closing metathesis (RCM) of N,N-diallyltosylamine and diethyl diallylmalonate in glycerol, under microwave irradiation and in the presence of the most common commercially available RCM catalysts. The products were isolated in high yield after extraction and the catalyst could be recycled up to two times. Results with simultaneous cooling of the reaction vessel under microwave irradiation are also reported.

Dates et versions

hal-00494415 , version 1 (23-06-2010)

Identifiants

Citer

Naoual Bakhrou, Frédéric Lamaty, Jean Martinez, Evelina Colacino. Ring closing metathesis reaction in glycerol under microwave activation. Tetrahedron Letters, 2010, 51, pp.3935-3937. ⟨10.1016/j.tetlet.2010.05.101⟩. ⟨hal-00494415⟩
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