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Article Dans Une Revue Coordination Chemistry Reviews Année : 2007

Preparation of NHC-ruthenium complexes and their catalytic activity in metathesis reaction

Résumé

A detailed overview on the synthesis of four-, five- and six-membered, saturated and unsaturated N-heterocyclic carbenes used in the preparation of their corresponding ruthenium complexes (Grubbs' second-generation, Fischer-type, Hoveyda-Grubbs, homo and hetero-bimetallic) is presented both in solution and on solid support. The catalytic activity of the different complexes in ruthenium-catalyzed metathesis reaction is compared and explained by their structural features. (c) 2006 Elsevier B.V. All rights reserved.
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hal-00423349 , version 1 (09-10-2009)

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Evelina Colacino, Jean Martinez, Frédéric Lamaty. Preparation of NHC-ruthenium complexes and their catalytic activity in metathesis reaction. Coordination Chemistry Reviews, 2007, 251 (5-6), pp.726-764. ⟨10.1016/ccr.2006.07.017⟩. ⟨hal-00423349⟩
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