Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile? - Archive ouverte HAL
Article Dans Une Revue The Journal of Chemical Physics Année : 2009

Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile?

Résumé

We present here the results of time-resolved absorption and emission experiments for 4-(dimethylamino)benzonitrile in solution, which suggest that the fluorescent intramolecular charge transfer (ICT) state may differ from the twisted ICT (TICT) state observed in transient absorption.

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Chimie théorique et/ou physique

Caroline Lebe  : Connectez-vous pour contacter le contributeur

https://hal.science/hal-00415167

Soumis le : jeudi 10 septembre 2009-13:49:05

Dernière modification le : mercredi 15 mai 2024-12:40:28

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Dates et versions

hal-00415167 , version 1 (10-09-2009)

Identifiants

Citer

T. Gustavsson, P.-B. Coto, L. Serrano-Andres, Taiga Fujiwara, E.-C. Lim. Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile?. The Journal of Chemical Physics, 2009, 131 (3), pp.031101. ⟨10.1063/1.3173609⟩. ⟨hal-00415167⟩

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