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Article Dans Une Revue Inorganic Chemistry Année : 2009

Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)−carboxylate complex

Résumé

The very fast and efficient water vapor absorption of the dimeric fluorous copper(II)-carboxylate complex [Cu(2)(C(8)F(17)CO(2))(4)(acetone)(2)] (1) leads, in the solid state, to a dramatic decrease of the exchange magnetic coupling between the copper(II) ions and to a drastic change of its powder EPR spectrum.

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Matériaux
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Dates et versions

hal-00414553 , version 1 (09-09-2009)

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Artur Motreff, Rosenildo Correa da Costa, Hassan Allouchi, Mathieu Duttine, Corine Mathonière, et al.. Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)−carboxylate complex. Inorganic Chemistry, 2009, 48 (13), pp.5623-5625. ⟨10.1021/ic9005218⟩. ⟨hal-00414553⟩
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