Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene - Archive ouverte HAL
Article Dans Une Revue Journal of Polymer Science Part A: Polymer Chemistry Année : 2006

Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene

Résumé

Novel water-soluble ruthenium carbene complexes with finely tuned structure and properties in solution are reported. These ruthenium-based initiators were found to exhibit great catalytic activity in aqueous miniemulsion ring-opening metathesis polymerization of norbornene. Stable particles of polynorbornene could be generated in the 200-250 nm size range stabilized with a nonionic surfactant (polystyrene-b-poly(ethylene oxide)).

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Dominique RICHARD  : Connectez-vous pour contacter le contributeur

https://hal.science/hal-00369223

Soumis le : mercredi 18 mars 2009-16:53:08

Dernière modification le : mercredi 15 mai 2024-14:22:03

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hal-00369223 , version 1 (18-03-2009)

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Damien Quemener, Valérie Héroguez, Yves Gnanou. Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the "macromonomer method" and application in the miniemulsion metathesis polymerization of norbornene. Journal of Polymer Science Part A: Polymer Chemistry, 2006, 44 (9), pp.2784-2793. ⟨10.1002/pola.21370⟩. ⟨hal-00369223⟩

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