Soil alkalinisation generally constitutes a major threat to irrigated agriculture in the semi-arid regions of West Africa. The improvement of sodic soils is generally difficult and expensive. However, a recent study in the Niger valley in NIGER, reveals that a natural de-alkalinisation is possible under natural conditions in a semi-arid climate. Transformation of non-saline sodic soil into brown steppe soil type was recorded. On the same site, the cultivation of a Sahelian fodder grass, locally known as “Burgu” was used on the sodic soil/brown steppe soil transition zone to accelerate this natural de-alkalinisation and characterise its mechanisms. The geochemical properties of both soil types were monitored before cultivation and one year after continuous crop cultivation. After cultivation and regular irrigation, the chemical properties of the former sodic soils were close to those of the surrounding brown steppe soils, which are better suited for agriculture. This modification of the sodic soil properties can be attributed to (i) the large amount of water supplied during cultivation that induced salt leaching. This is the main phenomenon responsible for the changes observed; (ii) the root activity that modified the acid-base equilibrium and consumes alkalinity. The Residual Alkalinity (RA) concept was used to select chemical tracers of the concentration/dilution of the soil solution. Here, sodium amount and calcite + fluorite residual alkalinity (RAcalcite+fluorite) were the most adequate ones. These two tracers decreased proportionally under the influence of leaching, but the exchanges between cations and protons changed the RAcalcite+fluorite, without modifying the sodium amount. Their combined use allowed us to separate and quantify the uptake of the plant from the leaching in the de-alkalinisation process. This study highlighted that reclamation of this type of sodic soils is feasible. The use of the RA concept is advisable to design a sustainable management system for irrigated sodic or saline soils.