Formation of TiO2 domains in poly (9-vinylcarbazole) thin film by hydrolysis-condensation of a metal alkoxyde - Archive ouverte HAL
Article Dans Une Revue Thin Solid Films Année : 2007

Formation of TiO2 domains in poly (9-vinylcarbazole) thin film by hydrolysis-condensation of a metal alkoxyde

Résumé

New organic-inorganic hybrid thin films based on Poly (9-vinylcarbazole) (P9VK) and Dioxide titanium (TiO2) bulk-heterojunction were obtained by a hydrolysis-condensation (H-C) process of titanium (IV) isopropoxide in thin film. The TiO2 distribution in the film was investigated by scanning electron microscopy. The results indicated that homogeneous TiO2 particles around 100 nm were formed on the surface of the polymer thin film. Photoluminescence spectroscopy has been used to study the charge transfer efficiency in the photoactive layer and results were compared with a simplest elaboration route, the dispersion of TiO2 anatase in a P9VK solution before spin coating. Results showed that TiO2 elaborated by H-C exhibits a competitive quenching effect with TiO2 anatase.

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Dates et versions

hal-00360361 , version 1 (11-02-2009)

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Vincent Barlier, Véronique Bounor-Legaré, Pierre Alcouffe, Gisèle Boiteux, Joel Davenas. Formation of TiO2 domains in poly (9-vinylcarbazole) thin film by hydrolysis-condensation of a metal alkoxyde. Thin Solid Films, 2007, 515 (16), pp.6328-6331. ⟨10.1016/j.tsf.2006.11.101⟩. ⟨hal-00360361⟩
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