C-H Oxidation by Hydroxo Manganese(V) Porphyrins. A DFT Study.
Résumé
A DFT study on toluene oxidation by Mn(V) porphyrins shows that both MnV(O) and, remarkably, also MnV(OH) are potent H atom abstractors.
A DFT study on toluene oxidation by Mn(V) porphyrins shows that both MnV(O) and, remarkably, also MnV(OH) are potent H atom abstractors.
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https://hal.science/hal-00357265
Soumis le : jeudi 29 janvier 2009-20:13:33
Dernière modification le : jeudi 28 novembre 2024-16:28:03