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Article Dans Une Revue Journal of Organometallic Chemistry Année : 2008

Dithiafulvenylphosphine as P- and P,S-ligand towards metal carbonyl fragments

Résumé

The ability of the dithiafulvenylphosphine (P-DTF) to react as a monodentate (P) or a bidentate (P,S) ligand with metal carbonyl complexes such as Mo(CO)6 and MnBr(CO)5 is presented. A series of metal carbonyl complexes are synthesised and characterised by IR, 1H NMR and 31P NMR spectroscopy. X-ray crystallographic analyses on the Mo(CO)5(P-DTF) and Mo(CO)4(P,S-DTF) complexes are reported together with the structural investigations on the dithiafulvenes precursors. The electrochemical properties of the various complexes investigated by cyclic voltammetry are discussed.

Domaines

Chimie organique

Dates et versions

hal-00343731 , version 1 (02-12-2008)

Identifiants

Citer

Michel Guerro, Emmanuel Di Piazza, Xin Jiang, Thierry Roisnel, Dominique Lorcy. Dithiafulvenylphosphine as P- and P,S-ligand towards metal carbonyl fragments. Journal of Organometallic Chemistry, 2008, 693 (13), pp.2345-2350. ⟨10.1016/j.jorganchem.2008.04.011⟩. ⟨hal-00343731⟩
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