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Article Dans Une Revue Chemical Physics Année : 2004

Application of the polarizability theory to the calculation of anisotropic circular dichroism spectra

Résumé

We derive a general expression of the circular dichroism spectra of anisotropically distributed chiral molecules in the polarizability framework by introducing a tensorial rotational strength. Example calculation is carried out on an acridine-substituted Tröger base. It is shown that the circular dichroism is very sensitive to the direction propagation of the light beam.

Dates et versions

hal-00324472 , version 1 (25-09-2008)

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François Hache, Thibault Dartigalongue. Application of the polarizability theory to the calculation of anisotropic circular dichroism spectra. Chemical Physics, 2004, 303 (1-2), pp.197-203. ⟨10.1016/j.chemphys.2004.05.021⟩. ⟨hal-00324472⟩
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