SYNTHESIS OF VARIOUS TYPES OF FUNCTIONAL HETEROCYCLIC-COMPOUNDS BY DECOMPOSITION OF UNSATURATED PEROXIDES - COMPETITIVE REACTIONS - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Canadian Journal of Chemistry Année : 1995

SYNTHESIS OF VARIOUS TYPES OF FUNCTIONAL HETEROCYCLIC-COMPOUNDS BY DECOMPOSITION OF UNSATURATED PEROXIDES - COMPETITIVE REACTIONS

Laurent Lemée

Résumé

Decomposition of gamma-unsaturated substituted peroxides in a good hydrogen donor solvent can lead to two diastereoisomeric oxetans. An intramolecular 1,5 hydrogen shift followed by a cyclization may compete with the homolytic intramolecular substitution following the first addition step. The factors governing this never-reported competition are determined.
Fichier non déposé

Dates et versions

hal-00160760 , version 1 (07-07-2007)

Identifiants

  • HAL Id : hal-00160760 , version 1

Citer

Evelyne Montaudon, Laurent Lemée, Marie-Joseph Bourgeois. SYNTHESIS OF VARIOUS TYPES OF FUNCTIONAL HETEROCYCLIC-COMPOUNDS BY DECOMPOSITION OF UNSATURATED PEROXIDES - COMPETITIVE REACTIONS. Canadian Journal of Chemistry, 1995, 73 (2), pp.161-168. ⟨hal-00160760⟩
12 Consultations
0 Téléchargements

Partager

Gmail Facebook X LinkedIn More