Enzymatic resolution of 1,1-dimethoxybut-3-en-2-ol and 1,1-dimethoxypent-4-en-2-ol, alpha-hydroxyaldehyde precursors for aldol-type reactions
Résumé
Hydroxyacetals 2 and 3 were resolved by acylation with vinyl acetate in the presence of lipases in organic media. The reverse reaction, the enzymatic hydrolysis of the corresponding acetates, was also highly stereoselective and provided the opposite enantiomers
Domaines
Chimie organique| Origine | Fichiers produits par l'(les) auteur(s) |
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