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Does the environment around the H-cluster allow coordination of the pendant amine to the catalytic iron center in [FeFe] hydrogenases? Answers from theory.

Toshiko Miyake , Maurizio Bruschi , Ugo Cosentino , Carole Baffert , Vincent Fourmond , et al.
European Journal of Biochemistry, 2013, 18 (6), pp.693-700. ⟨10.1007/s00775-013-1014-4⟩
Journal articles istex hal-03023214v1
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The two CO-dehydrogenases of Thermococcus sp. AM4

Martino Benvenuti , Marta Meneghello , Chloé Guendon , Aurore Jacq-Bailly , Jae-Hun Jeoung , et al.
Biochimica biophysica acta (BBA) - Bioenergetics, 2020, pp.148188. ⟨10.1016/j.bbabio.2020.148188⟩
Journal articles hal-02537797v1

Mechanism of Protection of Catalysts Supported in Redox Hydrogel Films

Vincent Fourmond , Stéphanie Stapf , Huaiguang Li , Darren Buesen , James Birell , et al.
Journal of the American Chemical Society, 2015, 137 (16), pp 5494-5505. ⟨10.1021/jacs.5b01194⟩
Journal articles hal-01428049v1

The oxidative inactivation of FeFe hydrogenase reveals the flexibility of the H-cluster

Vincent Fourmond , Claudio Greco , Kateryna Sybirna , Carole Baffert , Po-Hung Wang , et al.
Nature Chemistry, 2014, 6 (4), pp.336 - 342. ⟨10.1038/NCHEM.1892⟩
Journal articles hal-01481520v1

Reductive activation of E. coli respiratory nitrate reductase

Pierre Ceccaldi , Julia Rendon , Christophe Léger , René Toci , Bruno Guigliarelli , et al.
Biochimica biophysica acta (BBA) - Bioenergetics, 2015, 1847 Issue 10, pp.1055-1063. ⟨10.1016/j.bbabio.2015.06.007⟩
Journal articles hal-01429839v1

H2 evolution and molecular electrocatalysts: determination of overpotentials and effect of homoconjugation.

Vincent Fourmond , Pierre-André Jacques , Marc Fontecave , Vincent Artero
Inorganic Chemistry, 2010, 49 (22), pp.10338-47. ⟨10.1021/ic101187v⟩
Journal articles hal-01069160v1

Rates of Intra- and Intermolecular Electron Transfers in Hydrogenase Deduced from Steady-State Activity Measurements

Sébastien Dementin , Bénédicte Burlat , Vincent Fourmond , Fanny Leroux , Pierre-Pol Liebgott , et al.
Journal of the American Chemical Society, 2011, 133 (26), pp.10211-10221
Journal articles hal-01977634v1
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Reactivity of the Excited States of the H-Cluster of FeFe Hydrogenases

Matteo Sensi , Carole Baffert , Claudio Greco , Giorgio Caserta , Charles Gauquelin , et al.
Journal of the American Chemical Society, 2016, 138 (41), pp.13612-13618. ⟨10.1021/jacs.6b06603⟩
Journal articles hal-01400732v1
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Numerical computations of Marcus–hush–Chidsey electron transfer rate constants

Vincent Fourmond , Christophe Léger
Journal of Electroanalytical Chemistry, In press, pp.114762. ⟨10.1016/j.jelechem.2020.114762⟩
Journal articles hal-02968022v1
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A new electrochemical cell with a uniformly accessible electrode to study fast catalytic reactions

Mariam Fadel , Daurelle Jean-Vincent , Vincent Fourmond , Jérôme Vicente
Physical Chemistry Chemical Physics, 2019, 21 (23), pp.12360-12371. ⟨10.1039/c9cp01487j⟩
Journal articles hal-02308533v1
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How Thermophilic Gram-Positive Organisms Perform Extracellular Electron Transfer: Characterization of the Cell Surface Terminal Reductase OcwA

N. L Costa , B. Hermann , V. Fourmond , M. Faustino , M. Teixeira , et al.
mBio, 2019, 10 (4), ⟨10.1128/mBio.01210-19⟩
Journal articles hal-02315696v1
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Understanding and Design of Bidirectional and Reversible Catalysts of Multielectron, Multistep Reactions

Vincent Fourmond , Eric S Wiedner , Wendy J Shaw , Christophe Léger
Journal of the American Chemical Society, 2019, ⟨10.1021/jacs.9b04854⟩
Journal articles hal-02179792v1

Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.

Sigolène Canaguier , Vincent Fourmond , Carlo U Perotto , Jennifer Fize , Jacques Pécaut , et al.
Chemical Communications, 2013, 49 (44), pp.5004-6. ⟨10.1039/c3cc40987b⟩
Journal articles hal-01069157v1

A "two-step'' chronoamperometric method for studying the anaerobic inactivation of an oxygen tolerant NiFe hydrogenase

Vincent Fourmond , Pascale Infossi , Marie-Thérèse Giudici-Orticoni , Patrick Bertrand , Christophe Léger
Journal of the American Chemical Society, 2010, 13 (132), pp.4848-4850
Journal articles hal-00677470v1
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Combining experimental and theoretical methods to learn about the reactivity of gas-processing metalloenzymes

Claudio Greco , Vincent Fourmond , Carole Baffert , Po-Hung Wang , Sébastien Dementin , et al.
Energy & Environmental Science, 2014, ⟨10.1039/c4ee01848f⟩
Journal articles hal-01211585v1

Protein Electrochemistry: Questions and Answers

Vincent Fourmond , Christophe Léger
Advances in Biochemical Engineering Biotechnology, 2016, Advances in Biochemical Engineering/Biotechnology, pp.1-41. ⟨10.1007/10_2015_5016⟩
Journal articles hal-01413237v1
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Reversible H2 oxidation and evolution by hydrogenase embedded in a redox polymer film

Steffen Hardt , Stefanie Stapf , Dawit T Filmon , James A Birrell , Olaf Rüdiger , et al.
Nature Catalysis, 2021, 4, pp.251 - 258. ⟨10.1038/s41929-021-00586-1⟩
Journal articles hal-03215114v1

Relation between anaerobic inactivation and oxygen tolerance in a large series of NiFe hydrogenase mutants

A. Abou Hamdan , Pierre-Pol Liebgott , V. Fourmond , O. Gutierrez-Sanz , A. de Lacey , et al.
Proceedings of the National Academy of Sciences of the United States of America, 2012, 109 (49), pp.19916 - 19921. ⟨10.1073/pnas.1212258109⟩
Journal articles hal-01825482v1

Membrane-Bound Hydrogenase I from the Hyperthermophilic Bacterium Aquifex aeolicus: Enzyme Activation, Redox Intermediates and Oxygen Tolerance

M.E. Pandelia , Vincent Fourmond , Pascale Infossi , Elisabeth Lojou , Patrick Bertrand , et al.
Journal of the American Chemical Society, 2010, 132, pp.6991-7004. ⟨10.1021/ja910838d⟩
Journal articles hal-00686880v1
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Direct Electrochemistry of Molybdenum and Tungsten Enzymes

Vincent Fourmond
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2017, 2017, ⟨10.1016/B978-0-12-409547-2.13354-2⟩
Journal articles hal-01614270v1

Relating diffusion along the substrate tunnel and oxygen sensitivity in hydrogenase

Pierre-Pol Liebgott , Fanny Leroux , Bénédicte Burlat , Sébastien Dementin , Carole Baffert , et al.
Nature Chemical Biology, 2010, 6 (1), pp.63-70
Journal articles hal-01977629v1
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Photoinhibition of FeFe Hydrogenase

Matteo Sensi , Carole Baffert , Laura Fradale , Charles Gauquelin , Philippe Soucaille , et al.
ACS Catalysis, 2017, 7 (10), pp.7378-7387. ⟨10.1021/acscatal.7b02252⟩
Journal articles hal-01613876v1

Electrochemical Study of a reconstituted Photosynthetic Electron-Transfer Chain

V. Fourmond , B. Lagoutte , P. Setif , W. Leilb , C. Demaille
Journal of the American Chemical Society, 2007, pp.9201-9209
Journal articles hal-00207644v1

Activations réductives de la nitrate réductase périplasmique NapAB de Rhodobacter sphaeroides

Vincent Fourmond
congrès du Groupe Français de Bioélectrochimie, Sep 2008, Lacanau, France
Conference papers hal-00338568v1

Amélioration du transport de masse dans les électrodes à jet pour l’étude des enzymes très actives

Fadel Mariam , Daurelle Jean-Vincent , Vincent Fourmond , Vicente Jerome
SFT, May 2017, Marseille, France
Conference papers hal-01795384v1

The Carbon Monoxide Dehydrogenase from Desulfovibrio vulgaris

Jessica Hadj-Saïd , Maria-Eirini Pandelia , Christophe Léger , Vincent Fourmond , Sébastien Dementin
Biochimica biophysica acta (BBA) - Bioenergetics, 2015, 1847 (12), pp.1574 - 1583. ⟨10.1016/j.bbabio.2015.08.002⟩
Journal articles hal-01430965v1
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Optimizing the mass transport of wall-tube electrodes for protein film electrochemistry

Asmaa Hadj Ahmed , Jean-Vincent Daurelle , Vincent Fourmond
Electrochimica Acta, 2022, 403, pp.139521. ⟨10.1016/j.electacta.2021.139521⟩
Journal articles hal-03485431v1

Rates of intra and intermolecular electron transfers in hydrogenase deduced from steady-state activity measurements

Sébastien Dementin , Bénédicte Burlat , Vincent Fourmond , Fanny Leroux , Pierre-Pol Liebgott , et al.
Journal of the American Chemical Society, 2011, 133 (26), pp.10211-10221. ⟨10.1021/ja202615a⟩
Journal articles hal-00677402v1
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Electrochemical studies of CO 2 -reducing metalloenzymes

Marta Meneghello , Christophe Léger , Vincent Fourmond
Chemistry - A European Journal, 2021, ⟨10.1002/chem.202102702⟩
Journal articles hal-03358088v1
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Structural insight into metallocofactor maturation in carbon monoxide dehydrogenase

Elizabeth Wittenborn , Steven E Cohen , Meriem Merrouch , Christophe Léger , Vincent Fourmond , et al.
Journal of Biological Chemistry, In press, pp.jbc.RA119.009610. ⟨10.1074/jbc.RA119.009610⟩
Journal articles hal-02188452v1