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Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes

Alina A Grineva , Oleg A Filippov , Yves Canac , Jean-Baptiste Sortais , Sergei E Nefedov et al.
Inorganic Chemistry, 2021, 60 (6), pp.4015-4025. ⟨10.1021/acs.inorgchem.1c00073⟩
Journal articles hal-03200528v1

Manganese-mediated synthesis of an NHC core non-symmetric pincer ligand and evaluation of its coordination properties

Dmitry A. Valyaev , Jérémy Willot , Loïc P. Mangin , Davit Zargarian , Noël Lugan et al.
Dalton Transactions, 2017, 46 (31), pp.10193-10196. ⟨10.1039/C7DT02190A⟩
Journal articles hal-01938382v1
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Carbenes and phosphonium ylides: a fruitful association in coordination chemistry

Dmitry A. Valyaev , Yves Canac
Dalton Transactions, 2021, 50 (45), pp.16434-16442. ⟨10.1039/D1DT03155D⟩
Journal articles hal-03404061v1
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Half-sandwich manganese complexes Cp(CO) 2 Mn(NHC) as redox-active organometallic fragments

Rémy Brousses , Vincent Maurel , Jean-Marie Mouesca , Vincent César , Noël Lugan et al.
Dalton Transactions, 2021, 50 (40), pp.14264-14272. ⟨10.1039/D1DT02182F⟩
Journal articles hal-03403199v1

Umpolung of methylenephosphonium ions in their manganese half-sandwich complexes and application to the synthesis of chiral phosphorus-containing ligand scaffolds

Dmitry A. Valyaev , Oleg A. Filippov , Noël Lugan , Guy Lavigne , Nikolai A. Ustynyuk et al.
Angewandte Chemie International Edition, 2015, 127 (21), pp.6413-6417. ⟨10.1002/ange.201501256⟩
Journal articles istex hal-01909557v1
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Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H 2 activation

Nikolay Kireev , Oleg Filippov , Ekaterina Gulyaeva , Elena V Shubina , Laure Vendier et al.
Chemical Communications, 2020, 56 (14), pp.2139-2142. ⟨10.1039/c9cc07713h⟩
Journal articles hal-02489712v1
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Binuclear Cu(I) and Mn(0) Complexes with a Tridentate Pyridine-NHC-Phosphane Ligand in a µ-κ 2 Ĉ,N -M;κ 1 P -M Coordination Mode

Jérémy Willot , Noël Lugan , Dmitry A. Valyaev
European Journal of Inorganic Chemistry, 2019, 2019 (39-40), pp.4358-4364. ⟨10.1002/ejic.201900628⟩
Journal articles hal-02361486v1
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NHC Core Phosphonium Ylide-based Palladium(II) Pincer Complexes: The Second Ylide Extremity Makes the Difference

Rachid Taakili , Cécile Barthes , Amel Goëffon , Christine Lepetit , Carine Guyard-Duhayon et al.
Inorganic Chemistry, 2020, 59 (10), pp.7082-7096. ⟨10.1021/acs.inorgchem.0c00561⟩
Journal articles hal-02612432v1

Generation of α-Phosphinocarbene Complexes and Their Evolution: New Light on Relevant Isomerization Pathways

Dmitry A. Valyaev , Noël Lugan , Guy Lavigne , Nikolai Ustynyuk
Organometallics, 2008, 27 (20), pp.5180-5183. ⟨10.1021/om800884v⟩
Journal articles hal-03739911v1

Dual reactivity pattern of Mn(I) carbyne complexes Cp(CO)2Mn+≡C–R (R = Ar, Alk) vs. dppm: Subtle balance between double intramolecular nucleophilic addition and nucleophilic addition followed by migratory CO insertion

Dmitry A. Valyaev , Kamil I. Utegenov , Vassily V. Krivykh , Jérémy Willot , Nikolai A. Ustynyuk et al.
Journal of Organometallic Chemistry, 2018, 867, pp.353-358. ⟨10.1016/j.jorganchem.2017.12.029⟩
Journal articles hal-01948411v1

Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation

Dmitry A. Valyaev , Duo Wei , Saravanakumar Elangovan , Matthieu Cavailles , Vincent Dorcet et al.
Organometallics, 2016, 35 (24), pp.4090-4098. ⟨10.1021/acs.organomet.6b00785⟩
Journal articles hal-01475468v1
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Palladium( ii ) pincer complexes of a C , C , C -NHC, diphosphonium bis(ylide) ligand

Rachid Taakili , Christine Lepetit , Carine Guyard-Duhayon , Dmitry A. Valyaev , Noël Lugan et al.
Dalton Transactions, 2019, 48 (5), pp.1709-1721. ⟨10.1039/c8dt04316g⟩
Journal articles hal-02140710v1

Study of Redox-induced Reactions of Vinylidene and bis-Vinylidene Complexes of Manganese

M. Peterleitner , Dmitry A. Valyaev , L. Novikova , O. Semeikin , N. Ustynyuk et al.
Elektrokhimiya / Russian Journal of Electrochemistry, 2003, 39 (11), pp.1270-1277. ⟨10.1023/B:RUEL.0000003457.94205.c7⟩
Journal articles hal-03739943v1

Oxidative dehydrodimerization of manganese vinylidene complexes (η5-C5R5)(CO)(L)Mn=C=CHPh (R=Me, L=CO; R=H, L=PPh3)

Lyudmila Novikova , Mikhail Peterleitner , Karine Sevumyan , Oleg Semeikin , Dmitry A. Valyaev et al.
Applied Organometallic Chemistry, 2002, 16 (9), pp.530-536. ⟨10.1002/aoc.341⟩
Journal articles hal-03739954v1

Oxidative dehydrodimerization of rhenium vinylidene complex (η5-C5H5)(CO)2ReCC(H)Ph: two competitive routes of coupling of σ-phenylethynyl intermediate [(η5-C5H5)(CO)2ReCCPh]. X-ray structures of rhenium mononuclear (η5-C5H5)(CO)2ReCC(H)Ph and binuclear [(η5-C5H5)(CO)2Re]2(μ2-CC(Ph)CCPh) vinylidene compounds

Dmitry A. Valyaev , Oleg Semeikin , Mikhail Peterleitner , Yuri Borisov , Viktor Khrustalev et al.
Journal of Organometallic Chemistry, 2004, 689 (23), pp.3837-3846. ⟨10.1016/j.jorganchem.2004.07.038⟩
Journal articles hal-03739933v1
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Editorial overview: Smart use of metal reagents unlocks greener organic synthesis

Dmitry A. Valyaev
Current opinion in green and sustainable chemistry, 2021, 32, pp.100551. ⟨10.1016/j.cogsc.2021.100551⟩
Journal articles hal-03361826v1
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Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes

Ekaterina S Gulyaeva , Elena S Osipova , Ruqaya Buhaibeh , Yves Canac , Jean-Baptiste Sortais et al.
Coordination Chemistry Reviews, 2022, 458, pp.214421. ⟨10.1016/j.ccr.2022.214421⟩
Journal articles hal-03566299v1

Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s

Alina A Grineva , Dmitry A. Valyaev , Vincent César , O. A. Filippov , Victor N. Khrustalev et al.
Angewandte Chemie International Edition, 2018, 57 (27), pp.7986-7991. ⟨10.1002/anie.201801530⟩
Journal articles hal-01948415v1

A direct, modular, and efficient construction of the P-C-P structural motif through coupling of manganese carbyne complexes with phosphines

D.A. Valyaev , S. Bastin , K.I. Utegenov , Noël Lugan , Guy Lavigne et al.
Chemistry - A European Journal, 2014, 20 (8), pp.2175-2178. ⟨10.1002/chem.201304239⟩
Journal articles istex hal-00992333v1
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Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment

Ihor Kulai , Andrii Karpus , Liubov Soroka , Dmitry A. Valyaev , Valérie Bourdon et al.
Polymer Chemistry, 2019, 10 (2), pp.267-277. ⟨10.1039/c8py01279b⟩
Journal articles hal-02134244v1

Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases

Natalia Belkova , Evgenii Gutsul , Oleg Filippov , Vladislava Levina , Dmitry A. Valyaev et al.
Journal of the American Chemical Society, 2006, 128 (11), pp.3486-3487. ⟨10.1021/ja057867n⟩
Journal articles hal-03739923v1

Organometallic Manganese Compounds in Organic Synthesis

Alina A Grineva , Noël Lugan , Dmitry A. Valyaev
Jean-Baptiste Sortais. Manganese Catalysis in Organic Synthesis, Wiley-VCH, pp.1-37, 2021, 978-3-527-34730-8. ⟨10.1002/9783527826131.ch1⟩
Book sections hal-03376634v1
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Direct Access to IMes F and IMes F 2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes

Alina A Grineva , Oleg Filippov , Sergei Nefedov , Noël Lugan , Vincent César et al.
Organometallics, 2019, 38 (11), pp.2330-2337. ⟨10.1021/acs.organomet.9b00151⟩
Journal articles hal-02333068v1

Conformation of half-sandwich Mn(I) O-alkyl and O-aryl Fischer carbene complexes: a joined experimental-theoretical study

N. Lugan , I. Fernández , Dmitry A. Valyaev , R. Brousses , M. Sierra et al.
Acta Crystallographica Section A : Foundations of Crystallography [1968-2013], 2011, 67 (a1), pp.C452-C452. ⟨10.1107/S0108767311088611⟩
Journal articles hal-03739896v1

Post-coordination backbone functionalization of an imidazol-2-ylidene and its application to synthesize heteropolymetallic complexes incorporating the ambidentate IMes(CO2-) ligand

Dmitry A. Valyaev , Marina A. Uvarova , Alina A Grineva , Vincent César , Sergei N. Nefedov et al.
Dalton Transactions, 2016, 45 (30), pp.11953-11957. ⟨10.1039/c6dt02060g⟩
Journal articles hal-01925254v1

Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

Mirko Ruamps , S. Bastin , Lionel Rechignat , Alix Sournia-Saquet , Dmitry A. Valyaev et al.
Chemical Communications, 2018, 54 (55), pp.7653-7656. ⟨10.1039/C8CC03934H⟩
Journal articles hal-01948412v1

Redox induced reactions of transition metal vinylidene and related complexes

Dmitry A. Valyaev , Oleg Semeikin , Nikolai Ustynyuk
Coordination Chemistry Reviews, 2004, 248 (15-16), pp.1679-1692. ⟨10.1016/j.ccr.2004.08.008⟩
Journal articles hal-03739927v1
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Grafting a homogeneous transition metal catalyst onto a silicon AFM probe: a promising strategy for chemically constructive nanolithography

Dmitry A. Valyaev , Sylvain Clair , Lionel Patrone , Mathieu Abel , Louis Porte et al.
Chemical Science, 2013, 4, pp.2815-2821. ⟨10.1039/c3sc50979f⟩
Journal articles hal-00861617v1

Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes

Jianxia Zheng , Saravanakumar Elangovan , Dmitry A. Valyaev , Rémy Brousses , Vincent César et al.
Advanced Synthesis and Catalysis, 2014, 356 (5), pp.1093-1097. ⟨10.1002/adsc.201300905⟩
Journal articles istex hal-01114930v1
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Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis

Ruqaya Buhaibeh , Carine Guyard-Duhayon , Dmitry A. Valyaev , Jean-Baptiste Sortais , Yves Canac et al.
Organometallics, 2021, 40 (2), pp.231−241
Journal articles hal-03128901v1