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Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes
Alina A Grineva
,
Oleg A Filippov
,
Yves Canac
,
Jean-Baptiste Sortais
,
Sergei E Nefedov
et al.
Journal articles
hal-03200528v1
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Manganese-mediated synthesis of an NHC core non-symmetric pincer ligand and evaluation of its coordination properties
Dmitry A. Valyaev
,
Jérémy Willot
,
Loïc P. Mangin
,
Davit Zargarian
,
Noël Lugan
et al.
Journal articles
hal-01938382v1
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Carbenes and phosphonium ylides: a fruitful association in coordination chemistry
Dmitry A. Valyaev
,
Yves Canac
Journal articles
hal-03404061v1
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Half-sandwich manganese complexes Cp(CO) 2 Mn(NHC) as redox-active organometallic fragments
Rémy Brousses
,
Vincent Maurel
,
Jean-Marie Mouesca
,
Vincent César
,
Noël Lugan
et al.
Journal articles
hal-03403199v1
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Umpolung of methylenephosphonium ions in their manganese half-sandwich complexes and application to the synthesis of chiral phosphorus-containing ligand scaffolds
Dmitry A. Valyaev
,
Oleg A. Filippov
,
Noël Lugan
,
Guy Lavigne
,
Nikolai A. Ustynyuk
et al.
Journal articles
istex
hal-01909557v1
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Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H 2 activation
Nikolay Kireev
,
Oleg Filippov
,
Ekaterina Gulyaeva
,
Elena V Shubina
,
Laure Vendier
et al.
Journal articles
hal-02489712v1
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Binuclear Cu(I) and Mn(0) Complexes with a Tridentate Pyridine-NHC-Phosphane Ligand in a µ-κ 2 Ĉ,N -M;κ 1 P -M Coordination Mode
Jérémy Willot
,
Noël Lugan
,
Dmitry A. Valyaev
Journal articles
hal-02361486v1
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NHC Core Phosphonium Ylide-based Palladium(II) Pincer Complexes: The Second Ylide Extremity Makes the Difference
Rachid Taakili
,
Cécile Barthes
,
Amel Goëffon
,
Christine Lepetit
,
Carine Guyard-Duhayon
et al.
Journal articles
hal-02612432v1
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Generation of α-Phosphinocarbene Complexes and Their Evolution: New Light on Relevant Isomerization Pathways
Dmitry A. Valyaev
,
Noël Lugan
,
Guy Lavigne
,
Nikolai Ustynyuk
Journal articles
hal-03739911v1
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Dual reactivity pattern of Mn(I) carbyne complexes Cp(CO)2Mn+≡C–R (R = Ar, Alk) vs. dppm: Subtle balance between double intramolecular nucleophilic addition and nucleophilic addition followed by migratory CO insertion
Dmitry A. Valyaev
,
Kamil I. Utegenov
,
Vassily V. Krivykh
,
Jérémy Willot
,
Nikolai A. Ustynyuk
et al.
Journal articles
hal-01948411v1
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Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation
Dmitry A. Valyaev
,
Duo Wei
,
Saravanakumar Elangovan
,
Matthieu Cavailles
,
Vincent Dorcet
et al.
Journal articles
hal-01475468v1
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Palladium( ii ) pincer complexes of a C , C , C -NHC, diphosphonium bis(ylide) ligand
Rachid Taakili
,
Christine Lepetit
,
Carine Guyard-Duhayon
,
Dmitry A. Valyaev
,
Noël Lugan
et al.
Journal articles
hal-02140710v1
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Study of Redox-induced Reactions of Vinylidene and bis-Vinylidene Complexes of Manganese
M. Peterleitner
,
Dmitry A. Valyaev
,
L. Novikova
,
O. Semeikin
,
N. Ustynyuk
et al.
Journal articles
hal-03739943v1
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Oxidative dehydrodimerization of manganese vinylidene complexes (η5-C5R5)(CO)(L)Mn=C=CHPh (R=Me, L=CO; R=H, L=PPh3)
Lyudmila Novikova
,
Mikhail Peterleitner
,
Karine Sevumyan
,
Oleg Semeikin
,
Dmitry A. Valyaev
et al.
Journal articles
hal-03739954v1
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Oxidative dehydrodimerization of rhenium vinylidene complex (η5-C5H5)(CO)2ReCC(H)Ph: two competitive routes of coupling of σ-phenylethynyl intermediate [(η5-C5H5)(CO)2ReCCPh]. X-ray structures of rhenium mononuclear (η5-C5H5)(CO)2ReCC(H)Ph and binuclear [(η5-C5H5)(CO)2Re]2(μ2-CC(Ph)CCPh) vinylidene compounds
Dmitry A. Valyaev
,
Oleg Semeikin
,
Mikhail Peterleitner
,
Yuri Borisov
,
Viktor Khrustalev
et al.
Journal articles
hal-03739933v1
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Editorial overview: Smart use of metal reagents unlocks greener organic synthesis
Dmitry A. Valyaev
Journal articles
hal-03361826v1
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Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
Ekaterina S Gulyaeva
,
Elena S Osipova
,
Ruqaya Buhaibeh
,
Yves Canac
,
Jean-Baptiste Sortais
et al.
Journal articles
hal-03566299v1
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Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s
Alina A Grineva
,
Dmitry A. Valyaev
,
Vincent César
,
O. A. Filippov
,
Victor N. Khrustalev
et al.
Journal articles
hal-01948415v1
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A direct, modular, and efficient construction of the P-C-P structural motif through coupling of manganese carbyne complexes with phosphines
D.A. Valyaev
,
S. Bastin
,
K.I. Utegenov
,
Noël Lugan
,
Guy Lavigne
et al.
Journal articles
istex
hal-00992333v1
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Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment
Ihor Kulai
,
Andrii Karpus
,
Liubov Soroka
,
Dmitry A. Valyaev
,
Valérie Bourdon
et al.
Journal articles
hal-02134244v1
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Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases
Natalia Belkova
,
Evgenii Gutsul
,
Oleg Filippov
,
Vladislava Levina
,
Dmitry A. Valyaev
et al.
Journal articles
hal-03739923v1
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Organometallic Manganese Compounds in Organic Synthesis
Alina A Grineva
,
Noël Lugan
,
Dmitry A. Valyaev
Jean-Baptiste Sortais. Manganese Catalysis in Organic Synthesis, Wiley-VCH, pp.1-37, 2021, 978-3-527-34730-8. ⟨10.1002/9783527826131.ch1⟩
Book sections
hal-03376634v1
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Direct Access to IMes F and IMes F 2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes
Alina A Grineva
,
Oleg Filippov
,
Sergei Nefedov
,
Noël Lugan
,
Vincent César
et al.
Journal articles
hal-02333068v1
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Conformation of half-sandwich Mn(I) O-alkyl and O-aryl Fischer carbene complexes: a joined experimental-theoretical study
N. Lugan
,
I. Fernández
,
Dmitry A. Valyaev
,
R. Brousses
,
M. Sierra
et al.
Acta Crystallographica Section A : Foundations of Crystallography [1968-2013], 2011, 67 (a1), pp.C452-C452. ⟨10.1107/S0108767311088611⟩
Journal articles
hal-03739896v1
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Post-coordination backbone functionalization of an imidazol-2-ylidene and its application to synthesize heteropolymetallic complexes incorporating the ambidentate IMes(CO2-) ligand
Dmitry A. Valyaev
,
Marina A. Uvarova
,
Alina A Grineva
,
Vincent César
,
Sergei N. Nefedov
et al.
Journal articles
hal-01925254v1
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Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes
Mirko Ruamps
,
S. Bastin
,
Lionel Rechignat
,
Alix Sournia-Saquet
,
Dmitry A. Valyaev
et al.
Journal articles
hal-01948412v1
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Redox induced reactions of transition metal vinylidene and related complexes
Dmitry A. Valyaev
,
Oleg Semeikin
,
Nikolai Ustynyuk
Journal articles
hal-03739927v1
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Grafting a homogeneous transition metal catalyst onto a silicon AFM probe: a promising strategy for chemically constructive nanolithography
Dmitry A. Valyaev
,
Sylvain Clair
,
Lionel Patrone
,
Mathieu Abel
,
Louis Porte
et al.
Journal articles
hal-00861617v1
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Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes
Jianxia Zheng
,
Saravanakumar Elangovan
,
Dmitry A. Valyaev
,
Rémy Brousses
,
Vincent César
et al.
Journal articles
istex
hal-01114930v1
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Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis
Ruqaya Buhaibeh
,
Carine Guyard-Duhayon
,
Dmitry A. Valyaev
,
Jean-Baptiste Sortais
,
Yves Canac
et al.
Organometallics, 2021, 40 (2), pp.231−241
Journal articles
hal-03128901v1
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