<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of inserm-00264721</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-17T00:16:31+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Formation and rheological properties of the supercritical CO2-water pure interface.</title>
            <author role="crp">
              <persName>
                <forename type="first">Frédéric</forename>
                <surname>Tewes</surname>
              </persName>
              <email type="md5">07cfec3062c5f8729b5a2ed102f5357b</email>
              <email type="domain">univ-poitiers.fr</email>
              <idno type="idhal" notation="string">ftewes</idno>
              <idno type="idhal" notation="numeric">2100</idno>
              <idno type="halauthorid" notation="string">305557-2100</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-7865-718X</idno>
              <idno type="IDREF">https://www.idref.fr/133708772</idno>
              <idno type="VIAF">https://viaf.org/viaf/316664656</idno>
              <affiliation ref="#struct-3004"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Frank</forename>
                <surname>Boury</surname>
              </persName>
              <email type="md5">49450e43617814367c74ca7e674fcc7a</email>
              <email type="domain">univ-angers.fr</email>
              <idno type="idhal" notation="string">frank-boury</idno>
              <idno type="idhal" notation="numeric">750273</idno>
              <idno type="halauthorid" notation="string">293758-750273</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-3457-3988</idno>
              <affiliation ref="#struct-3004"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Frederic</forename>
                <surname>Tewes</surname>
              </persName>
              <email type="md5">07cfec3062c5f8729b5a2ed102f5357b</email>
              <email type="domain">univ-poitiers.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2008-03-17 16:50:04</date>
              <date type="whenModified">2024-07-17 08:30:30</date>
              <date type="whenReleased">2008-03-18 10:01:05</date>
              <date type="whenProduced">2005-03-10</date>
              <date type="whenEndEmbargoed">9999-12-31</date>
              <ref type="file" target="https://inserm.hal.science/inserm-00264721v1/document">
                <date notBefore="9999-12-31"/>
              </ref>
              <ref type="file" n="1" target="https://inserm.hal.science/inserm-00264721v1/file/Formation_and_Rheological_Properties_of_the_Supercritical_CO2-Water_Pure_Interface.pdf" id="file-264721-297941">
                <date notBefore="9999-12-31"/>
              </ref>
              <ref type="externalLink" target="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4767888"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="126777">
                <persName>
                  <forename>Frederic</forename>
                  <surname>Tewes</surname>
                </persName>
                <email type="md5">07cfec3062c5f8729b5a2ed102f5357b</email>
                <email type="domain">univ-poitiers.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">inserm-00264721</idno>
            <idno type="halUri">https://inserm.hal.science/inserm-00264721</idno>
            <idno type="halBibtex">tewes:inserm-00264721</idno>
            <idno type="halRefHtml">&lt;i&gt;Journal of Physical Chemistry B&lt;/i&gt;, 2005, 109 (9), pp.3990-7. &lt;a target="_blank" href="https://dx.doi.org/10.1021/jp046019w"&gt;&amp;#x27E8;10.1021/jp046019w&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Journal of Physical Chemistry B, 2005, 109 (9), pp.3990-7. &amp;#x27E8;10.1021/jp046019w&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-264721-297941"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="INSERM">INSERM - Institut national de la santé et de la recherche médicale</idno>
            <idno type="stamp" n="UNIV-ANGERS">Université d'Angers</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Formation and rheological properties of the supercritical CO2-water pure interface.</title>
                <author role="crp">
                  <persName>
                    <forename type="first">Frédéric</forename>
                    <surname>Tewes</surname>
                  </persName>
                  <email type="md5">07cfec3062c5f8729b5a2ed102f5357b</email>
                  <email type="domain">univ-poitiers.fr</email>
                  <idno type="idhal" notation="string">ftewes</idno>
                  <idno type="idhal" notation="numeric">2100</idno>
                  <idno type="halauthorid" notation="string">305557-2100</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-7865-718X</idno>
                  <idno type="IDREF">https://www.idref.fr/133708772</idno>
                  <idno type="VIAF">https://viaf.org/viaf/316664656</idno>
                  <affiliation ref="#struct-3004"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Frank</forename>
                    <surname>Boury</surname>
                  </persName>
                  <email type="md5">49450e43617814367c74ca7e674fcc7a</email>
                  <email type="domain">univ-angers.fr</email>
                  <idno type="idhal" notation="string">frank-boury</idno>
                  <idno type="idhal" notation="numeric">750273</idno>
                  <idno type="halauthorid" notation="string">293758-750273</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-3457-3988</idno>
                  <affiliation ref="#struct-3004"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">19508</idno>
                <idno type="issn">1520-6106</idno>
                <idno type="eissn">1520-5207</idno>
                <title level="j">Journal of Physical Chemistry B</title>
                <imprint>
                  <publisher>American Chemical Society</publisher>
                  <biblScope unit="volume">109</biblScope>
                  <biblScope unit="issue">9</biblScope>
                  <biblScope unit="pp">3990-7</biblScope>
                  <date type="datePub">2005-03-10</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1021/jp046019w</idno>
              <idno type="pubmed">16851455</idno>
              <idno type="pubmedcentral">PMC4767888</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="mesh">Carbon Dioxide</classCode>
              <classCode scheme="mesh">Kinetics</classCode>
              <classCode scheme="mesh">Rheology</classCode>
              <classCode scheme="mesh">Water</classCode>
              <classCode scheme="halDomain" n="sdv.sp">Life Sciences [q-bio]/Pharmaceutical sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>From the interfacial tension (gamma) measurement, we have analyzed the interfacial organization that occurs between pure H2O and pure CO2 from a kinetical and rheological point of view. This article is the followup to a previous one, where we showed that this equilibrated interface is composed of small H2O-CO2 cluster blocks [Tewes, F.; Boury, F. J. Phys. Chem. B 2004, 108, 2405]. By analyzing the variation of gamma with the square root of time, we found that the organization of the H2O-CO2 interface is, in the initial times, controlled by the diffusion of the CO2 molecules into the water. We compared the frictional coefficient determined from the measured CO2 diffusion coefficient with the frictional coefficient calculated from the Stokes equation (frictional ratio). From that, we concluded that it is a hydrated form of CO2 that diffuses and that the degree of hydration decreases with pressure. Rheological properties of the equilibrated interface vary with CO2 pressure, in the range of 50-90 bar, from a viscoelastic comportment to a purely elastic behavior, showing a change in the interfacial organization. The high equilibrium part of the elasticity (110 mN/m) obtained at 90 bar suggests a highly structured interface. Two phenomena could explain the interfacial rheological behavior: (i) an increase and a growth of the blocks H2O-CO2 cluster with the CO2 pressure or (ii) an increase in the interfacial capacity to form stable clusters under interfacial area compression.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-3004" status="OLD">
          <orgName>Ingénierie de la vectorisation particulaire</orgName>
          <desc>
            <address>
              <addrLine>Batiment IBT 10, Rue Andre Boquel 49100 Angers</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.u646.angers.inserm.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-74911" type="direct"/>
            <relation name="U646" active="#struct-303623" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-74911" status="VALID">
          <idno type="IdRef">026402920</idno>
          <idno type="ISNI">0000000122483363</idno>
          <idno type="ROR">https://ror.org/04yrqp957</idno>
          <orgName>Université d'Angers</orgName>
          <orgName type="acronym">UA</orgName>
          <date type="start">1971-10-25</date>
          <desc>
            <address>
              <addrLine>Université d'Angers - 40 Rue de Rennes, BP 73532 - 49035 Angers CEDEX 01</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-angers.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-303623" status="VALID">
          <idno type="IdRef">026388278</idno>
          <idno type="ROR">https://ror.org/02vjkv261</idno>
          <orgName>Institut National de la Santé et de la Recherche Médicale</orgName>
          <orgName type="acronym">INSERM</orgName>
          <desc>
            <address>
              <addrLine>101, rue de Tolbiac, 75013 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.inserm.fr</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>