<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-05595730</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-04-28T03:21:45+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Controlling the Nucleation of a Semicrystalline Polymer by Inducing Compartmentalization of Competitive Nucleating Agents</title>
            <author role="aut">
              <persName>
                <forename type="first">Arnaud Y.‐g.</forename>
                <surname>Delplanque</surname>
              </persName>
              <idno type="halauthorid">2968291-0</idno>
              <affiliation ref="#struct-573130"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Sandra</forename>
                <surname>Casale</surname>
              </persName>
              <idno type="halauthorid">568283-0</idno>
              <affiliation ref="#struct-541749"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Bruno</forename>
                <surname>Bresson</surname>
              </persName>
              <email type="md5">5afb4e88968f5b0d9203a4b03760c9ac</email>
              <email type="domain">gmail.com</email>
              <idno type="idhal" notation="string">bruno-bresson</idno>
              <idno type="idhal" notation="numeric">16379</idno>
              <idno type="halauthorid" notation="string">28010-16379</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-2314-0079</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=taTsgW8AAAAJ&amp;hl=fr&amp;oi=sra</idno>
              <idno type="IDREF">https://www.idref.fr/136808441</idno>
              <affiliation ref="#struct-541956"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Paolo</forename>
                <surname>Edera</surname>
              </persName>
              <email type="md5">9da87f9136d628ada3cc18cf38895fea</email>
              <email type="domain">espci.fr</email>
              <idno type="idhal" notation="string">paolo-edera</idno>
              <idno type="idhal" notation="numeric">1337330</idno>
              <idno type="halauthorid" notation="string">2613968-1337330</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-2307-0661</idno>
              <affiliation ref="#struct-573130"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Clément</forename>
                <surname>Guibert</surname>
              </persName>
              <email type="md5">2d44aa0575e2d45faef0459c27900087</email>
              <email type="domain">upmc.fr</email>
              <idno type="idhal" notation="numeric">1139844</idno>
              <idno type="halauthorid" notation="string">399326-1139844</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-4824-5854</idno>
              <idno type="IDREF">https://www.idref.fr/191294047</idno>
              <idno type="VIAF">https://viaf.org/viaf/2753145857204222922326</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/GBM-1436-2022</idno>
              <affiliation ref="#struct-541749"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Nathan</forename>
                <forename type="middle">J</forename>
                <surname>van Zee</surname>
              </persName>
              <email type="md5">560153ab7d9596f452eb68d49981b9a8</email>
              <email type="domain">espci.psl.eu</email>
              <idno type="idhal" notation="string">nathan-van-zee</idno>
              <idno type="idhal" notation="numeric">750600</idno>
              <idno type="halauthorid" notation="string">3545735-750600</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-7899-9163</idno>
              <affiliation ref="#struct-573130"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Nathan</forename>
                <surname>Van Zee</surname>
              </persName>
              <email type="md5">560153ab7d9596f452eb68d49981b9a8</email>
              <email type="domain">espci.psl.eu</email>
            </editor>
            <funder ref="#projanr-56731"/>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2026-04-17 18:28:43</date>
              <date type="whenModified">2026-04-28 03:19:58</date>
              <date type="whenReleased">2026-04-20 18:46:28</date>
              <date type="whenProduced">2025-09-15</date>
              <date type="whenEndEmbargoed">2026-04-17</date>
              <ref type="file" target="https://hal.science/hal-05595730v1/document">
                <date notBefore="2026-04-17"/>
              </ref>
              <ref type="file" subtype="publisherPaid" n="1" target="https://hal.science/hal-05595730v1/file/2025_VanZee_Small_Compartmentalization.pdf" id="file-5595730-4793318">
                <date notBefore="2026-04-17"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="1105539">
                <persName>
                  <forename>Nathan</forename>
                  <surname>Van Zee</surname>
                </persName>
                <email type="md5">560153ab7d9596f452eb68d49981b9a8</email>
                <email type="domain">espci.psl.eu</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-05595730</idno>
            <idno type="halUri">https://hal.science/hal-05595730</idno>
            <idno type="halBibtex">delplanque:hal-05595730</idno>
            <idno type="halRefHtml">&lt;i&gt;Small&lt;/i&gt;, 2025, 21 (43), pp.e07875. &lt;a target="_blank" href="https://dx.doi.org/10.1002/smll.202507875"&gt;&amp;#x27E8;10.1002/smll.202507875&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Small, 2025, 21 (43), pp.e07875. &amp;#x27E8;10.1002/smll.202507875&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://creativecommons.org/licenses/by-nc/4.0/">CC BY-NC 4.0 - Attribution - Non-commercial use<ref corresp="#file-5595730-4793318"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="ESPCI">ESPCI Paris-PSL</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="LRS" corresp="SORBONNE-UNIVERSITE">Laboratoire de Réactivité de Surface</idno>
            <idno type="stamp" n="SIMM" corresp="SORBONNE-UNIVERSITE">Sciences et Ingénierie de la Matière Molle - Physico-chimie des Polymères et Milieux Dispersés</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="PSL">Université Paris sciences et lettres</idno>
            <idno type="stamp" n="SORBONNE-UNIVERSITE">Sorbonne Université</idno>
            <idno type="stamp" n="SORBONNE-UNIV" corresp="SORBONNE-UNIVERSITE">Sorbonne Université 01/01/2018</idno>
            <idno type="stamp" n="SU-SCIENCES" corresp="SORBONNE-UNIVERSITE">Faculté des Sciences de Sorbonne Université</idno>
            <idno type="stamp" n="ESPCI-PSL" corresp="PSL">Ecole Supérieure de Physique et de Chimie Industrielles de la Ville de Paris - PSL</idno>
            <idno type="stamp" n="SU-TI">Sorbonne Université - Texte Intégral</idno>
            <idno type="stamp" n="ANR">ANR</idno>
            <idno type="stamp" n="ALLIANCE-SU"> Alliance Sorbonne Université</idno>
            <idno type="stamp" n="CHIMIE-SU" corresp="SORBONNE-UNIVERSITE">UFR de Chimie de Sorbonne-Université</idno>
            <idno type="stamp" n="SUPRA_PHYS_CHIMIE">Physico-Chimie</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Controlling the Nucleation of a Semicrystalline Polymer by Inducing Compartmentalization of Competitive Nucleating Agents</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Arnaud Y.‐g.</forename>
                    <surname>Delplanque</surname>
                  </persName>
                  <idno type="halauthorid">2968291-0</idno>
                  <affiliation ref="#struct-573130"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Sandra</forename>
                    <surname>Casale</surname>
                  </persName>
                  <idno type="halauthorid">568283-0</idno>
                  <affiliation ref="#struct-541749"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Bruno</forename>
                    <surname>Bresson</surname>
                  </persName>
                  <email type="md5">5afb4e88968f5b0d9203a4b03760c9ac</email>
                  <email type="domain">gmail.com</email>
                  <idno type="idhal" notation="string">bruno-bresson</idno>
                  <idno type="idhal" notation="numeric">16379</idno>
                  <idno type="halauthorid" notation="string">28010-16379</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-2314-0079</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=taTsgW8AAAAJ&amp;hl=fr&amp;oi=sra</idno>
                  <idno type="IDREF">https://www.idref.fr/136808441</idno>
                  <affiliation ref="#struct-541956"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Paolo</forename>
                    <surname>Edera</surname>
                  </persName>
                  <email type="md5">9da87f9136d628ada3cc18cf38895fea</email>
                  <email type="domain">espci.fr</email>
                  <idno type="idhal" notation="string">paolo-edera</idno>
                  <idno type="idhal" notation="numeric">1337330</idno>
                  <idno type="halauthorid" notation="string">2613968-1337330</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-2307-0661</idno>
                  <affiliation ref="#struct-573130"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Clément</forename>
                    <surname>Guibert</surname>
                  </persName>
                  <email type="md5">2d44aa0575e2d45faef0459c27900087</email>
                  <email type="domain">upmc.fr</email>
                  <idno type="idhal" notation="numeric">1139844</idno>
                  <idno type="halauthorid" notation="string">399326-1139844</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-4824-5854</idno>
                  <idno type="IDREF">https://www.idref.fr/191294047</idno>
                  <idno type="VIAF">https://viaf.org/viaf/2753145857204222922326</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/GBM-1436-2022</idno>
                  <affiliation ref="#struct-541749"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Nathan</forename>
                    <forename type="middle">J</forename>
                    <surname>van Zee</surname>
                  </persName>
                  <email type="md5">560153ab7d9596f452eb68d49981b9a8</email>
                  <email type="domain">espci.psl.eu</email>
                  <idno type="idhal" notation="string">nathan-van-zee</idno>
                  <idno type="idhal" notation="numeric">750600</idno>
                  <idno type="halauthorid" notation="string">3545735-750600</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-7899-9163</idno>
                  <affiliation ref="#struct-573130"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">18973</idno>
                <idno type="issn">1613-6810</idno>
                <idno type="eissn">1613-6829</idno>
                <title level="j">Small</title>
                <imprint>
                  <publisher>Wiley-VCH Verlag</publisher>
                  <biblScope unit="volume">21</biblScope>
                  <biblScope unit="issue">43</biblScope>
                  <biblScope unit="pp">e07875</biblScope>
                  <date type="datePub">2025-09-15</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1002/smll.202507875</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">supramolecular chemistry</term>
                <term xml:lang="en">nucleation</term>
                <term xml:lang="en">crystallization</term>
                <term xml:lang="en">coassembly</term>
                <term xml:lang="en">block copolymers</term>
              </keywords>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Many functional polymeric systems have been inspired by the principle of compartmentalization, a ubiquitous form of hierarchical assembly found in Nature. For instance, polymers have been elaborated with microcapsules that release a chemical payload upon activation by an external stimulus. A fascinating challenge it to design a polymeric system to perform the opposite function, i.e., to load a cargo into a dispersed minor phase. Herein, this concept is exemplified in the context of a semicrystalline polymer matrix that contains two nucleating agents, one based on a supramolecular assembly and another based on a covalent triblock copolymer. These two additives compete to nucleate the semicrystalline matrix according to their competitive nucleation efficiency. A functional copolymer is rationally designed to induce these two additives to spatially assemble together. By adding a small amount of the functional copolymer, the supramolecular assembly remarkably segregates to the block copolymer phase, which profoundly impacts the interface between the block copolymer phase and the matrix. The compartmentalized additives no longer exhibit nucleating properties for the matrix, and the resulting material shows essentially the same thermomechanical properties as the virgin matrix.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-573130" status="VALID">
          <idno type="IdRef">241778840</idno>
          <idno type="ISNI">0000000403674297</idno>
          <idno type="RNSR">200512549Y</idno>
          <idno type="ROR">https://ror.org/007sc9r91</idno>
          <orgName>Chimie Moléculaire, Macromoléculaire et Matériaux (UMR7167)</orgName>
          <orgName type="acronym">C3M</orgName>
          <date type="start">2001-01-01</date>
          <desc>
            <address>
              <addrLine>ESPCI, 10 rue Vauquelin 75005 Paris - Bat E 3ème étage</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.mmc.espci.fr/spip.php?rubrique79</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301585" type="direct"/>
            <relation active="#struct-564132" type="indirect"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR7167" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-541749" status="VALID">
          <idno type="IdRef">241292727</idno>
          <idno type="ISNI">0000000403699793</idno>
          <idno type="RNSR">200919198H</idno>
          <idno type="ROR">https://ror.org/04vthwx70</idno>
          <orgName>Laboratoire de Réactivité de Surface</orgName>
          <orgName type="acronym">LRS</orgName>
          <date type="start">2018-01-01</date>
          <desc>
            <address>
              <addrLine>Tour 54- 2ème etg 4 Place Jussieu - Case 178 75252 PARIS CEDEX 05</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://lrs.sorbonne-universite.fr/fr/index.html</ref>
          </desc>
          <listRelation>
            <relation active="#struct-341038" type="direct"/>
            <relation active="#struct-413221" type="direct"/>
            <relation name="UMR7197" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-541956" status="VALID">
          <idno type="IdRef">237883317</idno>
          <idno type="ISNI">0000000403700467</idno>
          <idno type="RNSR">199712660D</idno>
          <idno type="ROR">https://ror.org/03f0z1g15</idno>
          <orgName>Sciences et Ingénierie de la Matière Molle (UMR 7615)</orgName>
          <orgName type="acronym">SIMM</orgName>
          <date type="start">2018-01-01</date>
          <desc>
            <address>
              <addrLine>ESPCI, 10 rue Vauquelin 75231 PARIS CEDEX 05</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.simm.espci.fr/-Accueil-.html</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301585" type="direct"/>
            <relation active="#struct-564132" type="indirect"/>
            <relation active="#struct-341038" type="direct"/>
            <relation active="#struct-413221" type="direct"/>
            <relation name="UMR7615" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-301585" status="VALID">
          <idno type="IdRef">028114779</idno>
          <idno type="ISNI">000000009591493X</idno>
          <idno type="ROR">https://ror.org/03zx86w41</idno>
          <orgName>Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris</orgName>
          <orgName type="acronym">ESPCI Paris</orgName>
          <date type="start">1882-10-01</date>
          <desc>
            <address>
              <addrLine>10 rue Vauquelin, 75231 Paris cedex 05</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.espci.psl.eu/fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-564132" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-564132" status="VALID">
          <idno type="IdRef">241597595</idno>
          <idno type="ISNI">0000 0004 1784 3645</idno>
          <idno type="ROR">https://ror.org/013cjyk83</idno>
          <orgName>Université Paris Sciences et Lettres</orgName>
          <orgName type="acronym">PSL</orgName>
          <desc>
            <address>
              <addrLine>60 rue Mazarine 75006 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.psl.eu/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-413221" status="VALID">
          <idno type="IdRef">221333754</idno>
          <idno type="ROR">https://ror.org/02en5vm52</idno>
          <orgName>Sorbonne Université</orgName>
          <orgName type="acronym">SU</orgName>
          <date type="start">2018-01-01</date>
          <desc>
            <address>
              <addrLine>21 rue de l’École de médecine - 75006 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.sorbonne-universite.fr/</ref>
          </desc>
        </org>
      </listOrg>
      <listOrg type="projects">
        <org type="anrProject" xml:id="projanr-56731" status="VALID">
          <idno type="anr">ANR-21-CE06-0008</idno>
          <orgName>ANCHORS</orgName>
          <desc>Ancrage moléculaire de compatibilisants macromoléculaires fonctionnels</desc>
          <date type="start">2021</date>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>