N-centered, yet stable: an electronic structure investigation of FLP-type stabilized N₂O-based radicals
Résumé
The electrochemical one-electron reduction of IDipp•N#O (IDipp = 1,3-bis(2,6diisopropylphenyl)imidazol-2-ylidene) is inherently irreversible, highlighting the short-lived nature of the corresponding radical anion. However, stabilization by Lewis acidic boranes enables electrochemically reversible behavior, unlocking access to stable radical species. These radicals are synthesized via chemical reduction and fully characterized, revealing a highly N-centered nature alongside remarkable persistence at room temperature under an inert atmosphere. A comprehensive investigation of their electronic structure is presented, integrating electron paramagnetic resonance techniques (both continuous-wave and pulsed) with theoretical analysis to provide deeper insight into their properties.
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A comme version hal-05506586 Article Andrea Orellana Ben Amor, Laure Vendier, Vincent César, Vincent Maurel, Julien Panetier, et al.. N-centered, yet persistent: isolation of N 2 O-based radicals through FLP-type stabilization. Chemical Science, 2025, 17 (4), pp.2140 - 2147. ⟨10.1039/d5sc08152a⟩. ⟨hal-05506586⟩