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              <p>This study deals with the synthesis of an ecofriendly ZnO/zeolite nanocomposite (NC) using the impregnation methodfor the degradation of paracetamol (PAM) by photocatalysis. This drug, recognized as a persistent organic pollutant, is widely detected in wastewater and surface water. The obtained photocatalyst was characterized by FTIR, XRD, XPS, SEM-EDX, UV Vis, and photoluminescence (PL) techniques. Crystallite size of about 49.3 nm proved the successful dispersion of ZnO on the surface of the zeolite support. The effect of various operating conditions (e.g., pH, photocatalyst dosage, and initial paracetamol concentration) on the PAM degradation was determined using an experimental design model. The results revealed that the maximum paracetamol removal efficiency of 98% was achieved under UV irradiation and 100% after 180 minutes of exposure to sunlight using the ZnO/zeolite NC 50wt%/50wt%) at 22°C, under optimal conditions, including a catalyst loading of 0.67 g.L-1, an initial concentration of 40 mg.L-1, and a pH of 8.39. The degradation process followed first-order kinetics. Additionally, free radical scavenging tests indicated that the supported ZnO on zeolite enhanced the photocatalytic activity, due to the zeolite's internal electric field, which prevents the recombination of electrons and holes (e−/h+).In terms of pollutant parameter removal,the application of photocatalysis under UV and sunlight irradiations demonstrated a removal of Total organic carbon (TOC) of 57% and 56%,respectively,for aqueous solution and 27% and 39%, respectively, for pharmaceutical industry wastewater (PIWW). This study highlights the potential of ZnO/zeolite NC as a photocatalyst for efficient paracetamol removal and pollutant degradation under both UV and sunlight, and demonstrated its strong potential for regeneration since it can be recycled several times (Fourth cycles), offering a sustainable, eco-friendliness, and cost-effectiveness solution for pharmaceutical industry wastewater treatment.</p>
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