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                <title level="j">Physical Review Letters</title>
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                  <publisher>American Physical Society</publisher>
                  <biblScope unit="volume">135</biblScope>
                  <biblScope unit="issue">11</biblScope>
                  <biblScope unit="pp">113001</biblScope>
                  <date type="datePub">2025</date>
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              <p>A low-energy storage ring with an ultracold electron cooler has been coupled with a heavy-ion accelerator facilitating high-resolution electron-ion collision spectroscopy of the heaviest few-electron ions. In the present Letter resonant electron-ion recombination of berylliumlike Pb&lt;sup&gt;78+&lt;/sup&gt; ions was measured in the collision-energy range 9.3–16.5 eV and a value of 244.937(30) eV is derived for the Pb&lt;sup&gt;78+&lt;/sup&gt;(2s&lt;sup&gt;2&lt;/sup&gt; &lt;sup&gt;1&lt;/sup&gt;S&lt;sub&gt;0&lt;/sub&gt;-2s2p&lt;sup&gt;3&lt;/sup&gt;P&lt;sub&gt;1&lt;/sub&gt;) excitation energy. This result agrees with the most recent (less accurate) theoretical value of 244.942(52) eV [Malyshev et al., Phys. Rev. A 110, 062824 (2024)], which has been calculated by applying strong-field QED rigorously up to the second order. The present investigation suggests that further technical improvements can potentially increase the experimental accuracy by an order of magnitude.</p>
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