A non-innocent, π-extended N-heterobicyclic carbene–thiolate ligand
Résumé
A bidentate NHC-thiolate ligand based on the imidazo[1,5-a]pyridine scaffold and featuring an extended p-system is described. It is derived from a readily available zwitterionic precursor and the chemistry of the corresponding homoleptic Ni(II) complex is investigated.
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