<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-05165162</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-15T18:30:56+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Case-II diffusion and solvent-polymer films drying: A meso-scale model</title>
            <author role="aut">
              <persName>
                <forename type="first">Mireille</forename>
                <surname>Souche</surname>
              </persName>
              <idno type="halauthorid">3650810-0</idno>
              <affiliation ref="#struct-1199673"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Didier</forename>
                <surname>Long</surname>
              </persName>
              <email type="md5">4caf6663243da27621b9d324b5a7b492</email>
              <email type="domain">insa-lyon.fr</email>
              <idno type="idhal" notation="string">didier-long</idno>
              <idno type="idhal" notation="numeric">748328</idno>
              <idno type="halauthorid" notation="string">1625918-748328</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-3013-6852</idno>
              <idno type="IDREF">https://www.idref.fr/088735559</idno>
              <idno type="VIAF">https://viaf.org/viaf/310527887</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=HbRz-8IAAAAJ</idno>
              <affiliation ref="#struct-31551"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Didier</forename>
                <surname>Long</surname>
              </persName>
              <email type="md5">4caf6663243da27621b9d324b5a7b492</email>
              <email type="domain">insa-lyon.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2025-07-16 11:53:00</date>
              <date type="whenModified">2025-07-17 03:16:48</date>
              <date type="whenReleased">2025-07-16 12:09:21</date>
              <date type="whenProduced">2007-02-25</date>
              <date type="whenEndEmbargoed">2025-07-16</date>
              <ref type="file" target="https://hal.science/hal-05165162v1/document">
                <date notBefore="2025-07-16"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-05165162v1/file/solvent_rev_2.pdf" id="file-5165162-4456589">
                <date notBefore="2025-07-16"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="489737">
                <persName>
                  <forename>Didier</forename>
                  <surname>Long</surname>
                </persName>
                <email type="md5">4caf6663243da27621b9d324b5a7b492</email>
                <email type="domain">insa-lyon.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-05165162</idno>
            <idno type="halUri">https://hal.science/hal-05165162</idno>
            <idno type="halBibtex">souche:hal-05165162</idno>
            <idno type="halRefHtml">&lt;i&gt;EPL - Europhysics Letters&lt;/i&gt;, 2007, 77 (4), pp.48002. &lt;a target="_blank" href="https://dx.doi.org/10.1209/0295-5075/77/48002"&gt;&amp;#x27E8;10.1209/0295-5075/77/48002&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">EPL - Europhysics Letters, 2007, 77 (4), pp.48002. &amp;#x27E8;10.1209/0295-5075/77/48002&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-5165162-4456589"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-LYON1">Université Claude Bernard - Lyon I</idno>
            <idno type="stamp" n="INSA-LYON">Institut National des Sciences Appliquées de Lyon</idno>
            <idno type="stamp" n="MATEIS" corresp="UNIV-LYON1">Matériaux, ingénierie et sciences [Villeurbanne] </idno>
            <idno type="stamp" n="MATEIS_PVMH" corresp="MATEIS">Equipe PVMH </idno>
            <idno type="stamp" n="INSA-GROUPE">Groupe INSA</idno>
            <idno type="stamp" n="UDL">UDL</idno>
            <idno type="stamp" n="UNIV-LYON">Université de Lyon</idno>
            <idno type="stamp" n="GS-PHYSIQUE">Graduate School Physique</idno>
            <idno type="stamp" n="LPSO">Laboratoire de Physique des Solides d'Orsay</idno>
            <idno type="stamp" n="URP-LPS">Laboratoire de Psychologie Sociale : contextes et régulation</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Case-II diffusion and solvent-polymer films drying: A meso-scale model</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Mireille</forename>
                    <surname>Souche</surname>
                  </persName>
                  <idno type="halauthorid">3650810-0</idno>
                  <affiliation ref="#struct-1199673"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Didier</forename>
                    <surname>Long</surname>
                  </persName>
                  <email type="md5">4caf6663243da27621b9d324b5a7b492</email>
                  <email type="domain">insa-lyon.fr</email>
                  <idno type="idhal" notation="string">didier-long</idno>
                  <idno type="idhal" notation="numeric">748328</idno>
                  <idno type="halauthorid" notation="string">1625918-748328</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-3013-6852</idno>
                  <idno type="IDREF">https://www.idref.fr/088735559</idno>
                  <idno type="VIAF">https://viaf.org/viaf/310527887</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=HbRz-8IAAAAJ</idno>
                  <affiliation ref="#struct-31551"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">13149</idno>
                <idno type="issn">0295-5075</idno>
                <idno type="eissn">1286-4854</idno>
                <title level="j">EPL - Europhysics Letters</title>
                <imprint>
                  <publisher>European Physical Society / EDP Sciences / Società Italiana di Fisica / IOP Publishing</publisher>
                  <biblScope unit="volume">77</biblScope>
                  <biblScope unit="issue">4</biblScope>
                  <biblScope unit="pp">48002</biblScope>
                  <date type="datePub">2007-02-25</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1209/0295-5075/77/48002</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">diffusive momentum transport. . 61.41.+e -Polymers elastomers and plastics</term>
                <term xml:lang="en">diffusive momentum transport. . 61.41.+e -Polymers</term>
                <term xml:lang="en">elastomers</term>
                <term xml:lang="en">and plastics</term>
                <term xml:lang="en">. 83.80.Rs -Polymer solutions. . 66.20.+d -Viscosity of liquids</term>
              </keywords>
              <classCode scheme="halDomain" n="phys">Physics [physics]</classCode>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>&lt;div&gt;&lt;p&gt;We propose a model for calculating a constitutive relation for the dynamics of solvent-polymer systems close to the glass transition. We do it by considering a layer of thickness ξ of a few nanometers which is submitted to an arbitrary time varying solvent activity a(t). We show then how these constitutive relations allow to explain case-II diffusion in glassy polymers and provide a physical interpretation for the parameters of the Thomas-Windle model. Regarding the process of film drying, we show that films up to 1µm thick can be almost completely dried in an accessible experimental time, even at temperatures well below the polymer glass transition temperature. This is a consequence: 1-of the presence of the fast path 2-of the film being out equilibrium, and in a dynamical state which is must faster than the one it would have at equilibrium. When drying a thicker film, we show that a glassy crust may appear on the free surface, as has been shown experimentally.&lt;/p&gt;&lt;/div&gt;</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="researchteam" xml:id="struct-1199673" status="VALID">
          <orgName>Laboratoire de Physique des Solides - IDMAG</orgName>
          <orgName type="acronym">LPS</orgName>
          <date type="start">2020-01-01</date>
          <desc>
            <address>
              <addrLine>Bat. 510 91405 Orsay cedex</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-1051087" type="direct"/>
            <relation active="#struct-419361" type="indirect"/>
            <relation name="UMR8502" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-31551" status="VALID">
          <idno type="IdRef">149732341</idno>
          <idno type="ISNI">0000000102922242</idno>
          <idno type="RNSR">197311954R</idno>
          <idno type="ROR">01rnfhz46</idno>
          <orgName>Matériaux, ingénierie et science [Villeurbanne]</orgName>
          <orgName type="acronym">MATEIS</orgName>
          <date type="start">2008-01-01</date>
          <desc>
            <address>
              <addrLine>Bâtiment Blaise Pascal 7, avenue Jean Capelle 69621 VILLEURBANNE CEDEX</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://mateis.insa-lyon.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-194495" type="direct"/>
            <relation active="#struct-301088" type="indirect"/>
            <relation active="#struct-219748" type="direct"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation name="UMR5510" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-1051087" status="VALID">
          <idno type="IdRef">155036955</idno>
          <idno type="ISNI">0000000094046552</idno>
          <idno type="RNSR">199812838T</idno>
          <idno type="ROR">https://ror.org/02dyaew97</idno>
          <idno type="Wikidata">Q3214477</idno>
          <orgName>Laboratoire de Physique des Solides</orgName>
          <orgName type="acronym">LPS</orgName>
          <date type="start">2020-01-01</date>
          <desc>
            <address>
              <addrLine>Bat. 510 91405 Orsay cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.lps.u-psud.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-419361" type="direct"/>
            <relation name="UMR8502" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-419361" status="VALID">
          <idno type="IdRef">241345251</idno>
          <idno type="ROR">https://ror.org/03xjwb503</idno>
          <orgName>Université Paris-Saclay</orgName>
          <desc>
            <address>
              <addrLine>Bâtiment Bréguet, 3 Rue Joliot Curie 2e ét, 91190 Gif-sur-Yvette</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.universite-paris-saclay.fr/fr</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-194495" status="VALID">
          <idno type="IdRef">026402823</idno>
          <idno type="ISNI">0000000121686185</idno>
          <idno type="ROR">https://ror.org/029brtt94</idno>
          <orgName>Université Claude Bernard Lyon 1</orgName>
          <orgName type="acronym">UCBL</orgName>
          <desc>
            <address>
              <addrLine>43, boulevard du 11 novembre 1918, 69622 Villeurbanne cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-lyon1.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301088" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301088" status="VALID">
          <idno type="ROR">https://ror.org/01rk35k63</idno>
          <orgName>Université de Lyon</orgName>
          <desc>
            <address>
              <addrLine>92 rue Pasteur - CS 30122, 69361 Lyon Cedex 07</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.universite-lyon.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-219748" status="VALID">
          <idno type="IdRef">052444724</idno>
          <idno type="ISNI">0000 0001 2292 0228</idno>
          <orgName>Institut National des Sciences Appliquées de Lyon</orgName>
          <orgName type="acronym">INSA Lyon</orgName>
          <date type="start">1957-03-18</date>
          <desc>
            <address>
              <addrLine>20 Avenue Albert Einstein, 69621 Villeurbanne cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insa-lyon.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301088" type="direct"/>
            <relation active="#struct-301232" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301232" status="VALID">
          <idno type="IdRef">162105150</idno>
          <orgName>Institut National des Sciences Appliquées</orgName>
          <orgName type="acronym">INSA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>