Article Dans Une Revue European Journal of Organic Chemistry Année : 2011

Sulfoximines as a Versatile Scaffold for Electrophilic Fluoroalkylating Reagents

Résumé

New electrophilic fluoroalkylating agents based on the sulfoximine skeleton as a common platform are described. We demonstrate the importance of the activating group, attached to the nitrogen, and its specificity for the fluorinated group to be delivered. As an application, a variety of unknown dichlorofluoro, bromodifluoro, and trifluoromethyl alkynes have been prepared using these reagents.

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hal-05123372 , version 1 (20-06-2025)

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Céline Urban, Frédéric Cadoret, Jean‐claude Blazejewski, Emmanuel Magnier. Sulfoximines as a Versatile Scaffold for Electrophilic Fluoroalkylating Reagents. European Journal of Organic Chemistry, 2011, 2011 (25), pp.4862-4867. ⟨10.1002/ejoc.201100503⟩. ⟨hal-05123372⟩
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