Article Dans Une Revue European Journal of Organic Chemistry Année : 2012

The New Age of Electrophilic Perfluoro­alk­ylation Reactions

Résumé

The introduction of a perfluoroalkyl group, with emphasis on the trifluoromethyl moiety, is a challenging topic. Of the synthetic methods available in the repertoire of chemists, electrophilic introduction was until recently the least developed. In five years, however, a renaissance of this chemistry has happened. This renewal has been made possible thanks to reports both of numerous new reagents (stable, easy tohandle and to prepare) and of easier preparation of older reagents. Their availability rapidly inspired highly original works involving their use, in particular with the help of catalysis. This virtuous spiral, as well as all these exciting new developments, is described in this microreview.

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Dates et versions

hal-05123366 , version 1 (20-06-2025)

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Yohan Macé, Emmanuel Magnier. The New Age of Electrophilic Perfluoro­alk­ylation Reactions. European Journal of Organic Chemistry, 2012, 2012 (13), pp.2479-2494. ⟨10.1002/ejoc.201101535⟩. ⟨hal-05123366⟩
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