First Isolation of Enantiopure Perfluoroalkylated Sulfilimines and Sulfoximines
Résumé
Mono-, di-and trifluoromethyl sulfilimines and sulfoximines have been isolated for the first time in enantiopure form by separation of the racemate by supercritical fluid chromatography. The electrophilic trifluoromethylating Shibata reagent has been prepared as a single enantiomer.
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45. First Isolation of Enantiopure Perfluoroalkylated Sulfilimines and Sulfoximines.pdf (175.59 Ko)
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