<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-05115328</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-15T20:20:04+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Synthesis of 1,3,5,2λ 5 ‐Triazaphosphinines by Intramolecular Cyclisation of ( N ‐Cyanophosphorimidoyl)guanidines and Diguanidinophosphonium Chlorides</title>
            <author role="aut">
              <persName>
                <forename type="first">Nicolas</forename>
                <surname>Inguimbert</surname>
              </persName>
              <email type="md5">9799306cc2fa1441f3c1e0a1c8ed7d8d</email>
              <email type="domain">univ-perp.fr</email>
              <idno type="idhal" notation="string">nicolas-inguimbert</idno>
              <idno type="idhal" notation="numeric">758591</idno>
              <idno type="halauthorid" notation="string">224696-758591</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-0309-9048</idno>
              <idno type="IDREF">https://www.idref.fr/144551632</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=-hMMAVMAAAAJ</idno>
              <idno type="VIAF">https://viaf.org/viaf/201228858</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/N-3703-2015</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/N-3703-2015</idno>
              <affiliation ref="#struct-107006"/>
              <affiliation ref="#struct-1004379"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Lothar</forename>
                <surname>Jäger</surname>
              </persName>
              <idno type="halauthorid">1506845-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Marc</forename>
                <surname>Taillefer</surname>
              </persName>
              <email type="md5">34f51d0f8a5ef638e20a1505057b522d</email>
              <email type="domain">enscm.fr</email>
              <idno type="idhal" notation="string">marc-taillefer</idno>
              <idno type="idhal" notation="numeric">840957</idno>
              <idno type="halauthorid" notation="string">213889-840957</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Matthias</forename>
                <surname>Biedermann</surname>
              </persName>
              <idno type="halauthorid">3586015-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Henri‐jean</forename>
                <surname>Cristau</surname>
              </persName>
              <idno type="halauthorid">3586016-0</idno>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Nicolas</forename>
                <surname>Inguimbert</surname>
              </persName>
              <email type="md5">9799306cc2fa1441f3c1e0a1c8ed7d8d</email>
              <email type="domain">univ-perp.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2025-06-16 17:37:41</date>
              <date type="whenModified">2026-02-07 05:31:24</date>
              <date type="whenReleased">2025-06-16 17:37:41</date>
              <date type="whenProduced">2004-11-15</date>
              <ref type="externalLink" target="https://api.istex.fr/ark:/67375/WNG-TK2G6LSS-T/fulltext.pdf?sid=hal"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="756051">
                <persName>
                  <forename>Nicolas</forename>
                  <surname>Inguimbert</surname>
                </persName>
                <email type="md5">9799306cc2fa1441f3c1e0a1c8ed7d8d</email>
                <email type="domain">univ-perp.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-05115328</idno>
            <idno type="halUri">https://hal.science/hal-05115328</idno>
            <idno type="halBibtex">inguimbert:hal-05115328</idno>
            <idno type="halRefHtml">&lt;i&gt;European Journal of Organic Chemistry&lt;/i&gt;, 2004, 2004 (23), pp.4870-4876. &lt;a target="_blank" href="https://dx.doi.org/10.1002/ejoc.200400217"&gt;&amp;#x27E8;10.1002/ejoc.200400217&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">European Journal of Organic Chemistry, 2004, 2004 (23), pp.4870-4876. &amp;#x27E8;10.1002/ejoc.200400217&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="EPHE">École Pratique des Hautes Études</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-PERP">Université Perpignan Via Domitia</idno>
            <idno type="stamp" n="GIP-BE">GIP Bretagne Environnement</idno>
            <idno type="stamp" n="AGROPOLIS">Agropolis</idno>
            <idno type="stamp" n="CRIOBE">Centre de Recherches Insulaires et Observatoire de l'Environnement</idno>
            <idno type="stamp" n="PSL">Université Paris sciences et lettres</idno>
            <idno type="stamp" n="TEST-DEV">TEST-DEV</idno>
            <idno type="stamp" n="EPHE-PSL" corresp="PSL">École Pratique des Hautes Études - PSL</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Synthesis of 1,3,5,2λ 5 ‐Triazaphosphinines by Intramolecular Cyclisation of ( N ‐Cyanophosphorimidoyl)guanidines and Diguanidinophosphonium Chlorides</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Nicolas</forename>
                    <surname>Inguimbert</surname>
                  </persName>
                  <email type="md5">9799306cc2fa1441f3c1e0a1c8ed7d8d</email>
                  <email type="domain">univ-perp.fr</email>
                  <idno type="idhal" notation="string">nicolas-inguimbert</idno>
                  <idno type="idhal" notation="numeric">758591</idno>
                  <idno type="halauthorid" notation="string">224696-758591</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-0309-9048</idno>
                  <idno type="IDREF">https://www.idref.fr/144551632</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=-hMMAVMAAAAJ</idno>
                  <idno type="VIAF">https://viaf.org/viaf/201228858</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/N-3703-2015</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/N-3703-2015</idno>
                  <affiliation ref="#struct-107006"/>
                  <affiliation ref="#struct-1004379"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Lothar</forename>
                    <surname>Jäger</surname>
                  </persName>
                  <idno type="halauthorid">1506845-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Marc</forename>
                    <surname>Taillefer</surname>
                  </persName>
                  <email type="md5">34f51d0f8a5ef638e20a1505057b522d</email>
                  <email type="domain">enscm.fr</email>
                  <idno type="idhal" notation="string">marc-taillefer</idno>
                  <idno type="idhal" notation="numeric">840957</idno>
                  <idno type="halauthorid" notation="string">213889-840957</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Matthias</forename>
                    <surname>Biedermann</surname>
                  </persName>
                  <idno type="halauthorid">3586015-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Henri‐jean</forename>
                    <surname>Cristau</surname>
                  </persName>
                  <idno type="halauthorid">3586016-0</idno>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">13072</idno>
                <idno type="issn">1434-193X</idno>
                <idno type="eissn">1099-0690</idno>
                <title level="j">European Journal of Organic Chemistry</title>
                <imprint>
                  <publisher>Wiley-VCH Verlag</publisher>
                  <biblScope unit="volume">2004</biblScope>
                  <biblScope unit="issue">23</biblScope>
                  <biblScope unit="pp">4870-4876</biblScope>
                  <date type="datePub">2004-11-15</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1002/ejoc.200400217</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halDomain" n="chim.orga">Chemical Sciences/Organic chemistry</classCode>
              <classCode scheme="halDomain" n="sdv.ee.sant">Life Sciences [q-bio]/Ecology, environment/Health</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Abstract The sodium phosphonium diylide Na[Ph 2 P(NCN) 2 ] ( 3 ) − the first example of a stabilised phosphonium diylide − was synthesised by treatment of sodium diphenylphosphide with 2 equiv. of cyanic azide. Compound 3 reacted with alkyl‐ and arylammonium salts [RR′NH 2 ]Cl {R = PhCH 2 , t Bu, Ph; R′ = H; RR′ = −[(CH 2 ) 2 O(CH 2 ) 2 ]−}. Depending on the molar ratios (1:1 or 1:2), ( N ‐cyano‐ P , P ‐diphenylphosphorimidoyl)guanidines Ph 2 P(NCN)N=C(NH 2 )NRR′ ( 8 ) or diguanidinodiphenylphosphonium chlorides [Ph 2 P{N=C(NH 2 )NRR′} 2 ]Cl ( 10 ) were formed. When molten, compounds 8 yielded new cyclic 1,3,5,2λ 5 ‐triazaphosphinines 11 . The fusion of compound 10 allowed the formation of the same 1,3,5,2λ 5 ‐triazaphosphinines 11 , along with the formation of NH 4 Cl or [PhNH 3 ]Cl. A crystal structure analysis of 4‐amino‐6‐morpholino‐2,2‐diphenyl‐1,3,5,2λ 5 ‐triazaphosphinine ( 11a ) revealed an almost planar six‐membered ring for the 1,3,5,2λ 5 ‐triazaphosphinine template. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2004)</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-107006" status="VALID">
          <idno type="IdRef">12406468X</idno>
          <idno type="ISNI">0000000405695219</idno>
          <idno type="RNSR">201019121V</idno>
          <idno type="ROR">https://ror.org/02tp7mm44</idno>
          <orgName>Centre de recherches insulaires et observatoire de l'environnement</orgName>
          <orgName type="acronym">CRIOBE</orgName>
          <date type="start">2010-01-01</date>
          <desc>
            <address>
              <addrLine>BP 1013 Papetoiai 98729 PAPETOAI</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.criobe.pf/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-101475" type="direct"/>
            <relation active="#struct-110691" type="direct"/>
            <relation active="#struct-564132" type="indirect"/>
            <relation name="UAR3278 / USR3278 / UMS3278" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-1004379" status="INCOMING">
          <orgName>INSERM U266</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-101475" status="VALID">
          <idno type="ROR">https://ror.org/03am2jy38</idno>
          <orgName>Université de Perpignan Via Domitia</orgName>
          <orgName type="acronym">UPVD</orgName>
          <desc>
            <address>
              <addrLine>52 avenue Paul Alduy - 66860 Perpignan Cedex 9</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-perp.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-110691" status="VALID">
          <idno type="IdRef">026375478</idno>
          <idno type="ISNI">0000000121955365</idno>
          <idno type="ROR">https://ror.org/046b3cj80</idno>
          <orgName>École Pratique des Hautes Études</orgName>
          <orgName type="acronym">EPHE</orgName>
          <date type="start">1868-01-01</date>
          <desc>
            <address>
              <addrLine>4-14 Rue Ferrus, 75014 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.ephe.fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-564132" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-564132" status="VALID">
          <idno type="IdRef">241597595</idno>
          <idno type="ISNI">0000 0004 1784 3645</idno>
          <idno type="ROR">https://ror.org/013cjyk83</idno>
          <orgName>Université Paris Sciences et Lettres</orgName>
          <orgName type="acronym">PSL</orgName>
          <desc>
            <address>
              <addrLine>60 rue Mazarine 75006 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.psl.eu/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>