<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-05083918</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-15T21:27:30+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Telomerization of vinylidene fluoride with alkyl (or aryl) trifluoromethanethiosulfonates</title>
            <author role="aut">
              <persName>
                <forename type="first">Bruno</forename>
                <surname>Ameduri</surname>
              </persName>
              <idno type="halauthorid">5333-0</idno>
              <affiliation ref="#struct-24492"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Thierry</forename>
                <surname>Billard</surname>
              </persName>
              <email type="md5">43c770433353f3290502f44cc42261c9</email>
              <email type="domain">univ-lyon1.fr</email>
              <idno type="idhal" notation="string">thierry-billard</idno>
              <idno type="idhal" notation="numeric">773456</idno>
              <idno type="halauthorid" notation="string">896092-773456</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-2937-9523</idno>
              <idno type="IDREF">https://www.idref.fr/129536881</idno>
              <idno type="VIAF">https://viaf.org/viaf/197270287</idno>
              <idno type="ISNI">http://isni.org/isni/0000000357319090</idno>
              <affiliation ref="#struct-24487"/>
              <affiliation ref="#struct-194495"/>
              <affiliation ref="#struct-441569"/>
              <affiliation ref="#struct-210962"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Bernard</forename>
                <surname>Langlois</surname>
              </persName>
              <idno type="halauthorid">2476124-0</idno>
              <affiliation ref="#struct-538274"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Thierry</forename>
                <surname>Billard</surname>
              </persName>
              <email type="md5">43c770433353f3290502f44cc42261c9</email>
              <email type="domain">univ-lyon1.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2025-05-26 07:22:39</date>
              <date type="whenModified">2025-05-27 03:20:25</date>
              <date type="whenReleased">2025-05-26 07:22:39</date>
              <date type="whenProduced">2002-11-12</date>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="342289">
                <persName>
                  <forename>Thierry</forename>
                  <surname>Billard</surname>
                </persName>
                <email type="md5">43c770433353f3290502f44cc42261c9</email>
                <email type="domain">univ-lyon1.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-05083918</idno>
            <idno type="halUri">https://hal.science/hal-05083918</idno>
            <idno type="halBibtex">ameduri:hal-05083918</idno>
            <idno type="halRefHtml">&lt;i&gt;Journal of Polymer Science Part A: Polymer Chemistry&lt;/i&gt;, 2002, 40 (24), pp.4538-4549. &lt;a target="_blank" href="https://dx.doi.org/10.1002/pola.10535"&gt;&amp;#x27E8;10.1002/pola.10535&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Journal of Polymer Science Part A: Polymer Chemistry, 2002, 40 (24), pp.4538-4549. &amp;#x27E8;10.1002/pola.10535&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-LYON1">Université Claude Bernard - Lyon I</idno>
            <idno type="stamp" n="UNIV-MONTP1">Université Montpellier I</idno>
            <idno type="stamp" n="UNIV-MONTP2">Université Montpellier II - Sciences et Techniques du Languedoc</idno>
            <idno type="stamp" n="INSA-LYON">Institut National des Sciences Appliquées de Lyon</idno>
            <idno type="stamp" n="ENSC-MONTPELLIER">Ecole Nationale Supérieure de Chimie de Montpellier</idno>
            <idno type="stamp" n="ICG">Institut Charles Gerhardt - Institut de Chimie Moléculaire et des Matériaux de Montpellier</idno>
            <idno type="stamp" n="CHIMIE">Chimie</idno>
            <idno type="stamp" n="ICBMS" corresp="UNIV-LYON1"> Institut de Chimie et Biochimie Moléculaires et Supramoléculaires</idno>
            <idno type="stamp" n="INSA-GROUPE">Groupe INSA</idno>
            <idno type="stamp" n="UDL">UDL</idno>
            <idno type="stamp" n="UNIV-LYON">Université de Lyon</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Telomerization of vinylidene fluoride with alkyl (or aryl) trifluoromethanethiosulfonates</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Bruno</forename>
                    <surname>Ameduri</surname>
                  </persName>
                  <idno type="halauthorid">5333-0</idno>
                  <affiliation ref="#struct-24492"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Thierry</forename>
                    <surname>Billard</surname>
                  </persName>
                  <email type="md5">43c770433353f3290502f44cc42261c9</email>
                  <email type="domain">univ-lyon1.fr</email>
                  <idno type="idhal" notation="string">thierry-billard</idno>
                  <idno type="idhal" notation="numeric">773456</idno>
                  <idno type="halauthorid" notation="string">896092-773456</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-2937-9523</idno>
                  <idno type="IDREF">https://www.idref.fr/129536881</idno>
                  <idno type="VIAF">https://viaf.org/viaf/197270287</idno>
                  <idno type="ISNI">http://isni.org/isni/0000000357319090</idno>
                  <affiliation ref="#struct-24487"/>
                  <affiliation ref="#struct-194495"/>
                  <affiliation ref="#struct-441569"/>
                  <affiliation ref="#struct-210962"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Bernard</forename>
                    <surname>Langlois</surname>
                  </persName>
                  <idno type="halauthorid">2476124-0</idno>
                  <affiliation ref="#struct-538274"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">16056</idno>
                <idno type="issn">0887-624X</idno>
                <idno type="eissn">1099-0518</idno>
                <title level="j">Journal of Polymer Science Part A: Polymer Chemistry</title>
                <imprint>
                  <publisher>Wiley</publisher>
                  <biblScope unit="volume">40</biblScope>
                  <biblScope unit="issue">24</biblScope>
                  <biblScope unit="pp">4538-4549</biblScope>
                  <date type="datePub">2002-11-12</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1002/pola.10535</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halDomain" n="chim.poly">Chemical Sciences/Polymers</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Abstract The photochemical‐induced telomerization of vinylidene fluoride (VDF) with cyclohexyl (or phenyl) trifluoromethanethiosulfonate (CF 3 SO 2 SR), leading to CF 3 (VDF) n SR telomers, where R stands for cyclohexyl or phenyl, is presented. These sulfurated transfer agents were synthesized by the reaction between sodium triflinate (CF 3 SO 2 Na) and disulfide in the presence of bromine. 19 F NMR spectroscopy enabled an assessment of the average degrees of telomerization (DP n ) of these telomers with a neat CF 3 end group as the label. These DP n values increased for higher [VDF] 0 /[CF 3 SO 2 SR] 0 initial molar ratios. Interestingly, the normal/reversed ratio of VDF units in these telomers was low. Finally, the cotelomerization of VDF and hexafluoropropylene with these transfer agents was successfully achieved, leading to original ω‐CF 3 fluoroelastomers, the thermal properties of which were investigated. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4538–4549, 2002</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-24492" status="OLD">
          <idno type="ISNI">0000000123688723</idno>
          <idno type="RNSR">200711918D</idno>
          <idno type="ROR">https://ror.org/028wq3277</idno>
          <orgName>Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier</orgName>
          <orgName type="acronym">ICGM ICMMM</orgName>
          <date type="start">2006-01-01</date>
          <date type="end">2014-12-31</date>
          <desc>
            <address>
              <addrLine>Place Eugène Bataillon - Bâtiment 17 - CC1700- 34095 Montpellier cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.icgm.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-42570" type="direct"/>
            <relation active="#struct-92690" type="direct"/>
            <relation active="#struct-300370" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR5253" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-24487" status="VALID">
          <idno type="IdRef">149115806</idno>
          <idno type="ISNI">0000000122475857</idno>
          <idno type="RNSR">200711911W</idno>
          <idno type="ROR">https://ror.org/00gj33s30</idno>
          <orgName>Institut de Chimie et Biochimie Moléculaires et Supramoléculaires</orgName>
          <orgName type="acronym">ICBMS</orgName>
          <date type="start">2006-01-01</date>
          <desc>
            <address>
              <addrLine>ICBMS UMR 5246 CNRS, Université de Lyon, Université Lyon 1, CNRS, INSA Lyon, CPE Lyon, bâtiment Lederer, 1 rue Victor Grignard, 69622 Villeurbanne Cedex, France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.icbms.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-194495" type="direct"/>
            <relation active="#struct-301088" type="indirect"/>
            <relation active="#struct-210962" type="direct"/>
            <relation active="#struct-219748" type="direct"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR5246" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-194495" status="VALID">
          <idno type="IdRef">026402823</idno>
          <idno type="ISNI">0000000121686185</idno>
          <idno type="ROR">https://ror.org/029brtt94</idno>
          <orgName>Université Claude Bernard Lyon 1</orgName>
          <orgName type="acronym">UCBL</orgName>
          <desc>
            <address>
              <addrLine>43, boulevard du 11 novembre 1918, 69622 Villeurbanne cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-lyon1.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301088" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-210962" status="VALID">
          <orgName>École Supérieure de Chimie Physique Électronique de Lyon</orgName>
          <orgName type="acronym">CPE</orgName>
          <desc>
            <address>
              <addrLine>Domaine Scientifique de la DouaBâtiment Hubert Curien 43 Boulevard du 11 Novembre 191869616 Villeurbanne</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cpe.fr/</ref>
          </desc>
        </org>
        <org type="regrouplaboratory" xml:id="struct-538274" status="VALID">
          <orgName>Université Claude Bernard Lyon 1 - Faculté des sciences</orgName>
          <orgName type="acronym">UCBL FS</orgName>
          <desc>
            <address>
              <addrLine>4 rue Victor Grignard - 69100 Villeurbanne</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://ufr-fs.univ-lyon1.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-194495" type="direct"/>
            <relation active="#struct-301088" type="indirect"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-42570" status="OLD">
          <orgName>Université Montpellier 1</orgName>
          <orgName type="acronym">UM1</orgName>
          <date type="end">2014-12-31</date>
          <desc>
            <address>
              <addrLine>5, boulevard Henri IV - CS 19044 - 34967 Montpellier cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-montp1.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-92690" status="OLD">
          <orgName>Université Montpellier 2 - Sciences et Techniques</orgName>
          <orgName type="acronym">UM2</orgName>
          <date type="end">2014-12-31</date>
          <desc>
            <address>
              <addrLine>Place Eugène Bataillon - 34095 Montpellier cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-montp2.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300370" status="OLD">
          <idno type="ROR">https://ror.org/03sgyqj04</idno>
          <orgName>Ecole Nationale Supérieure de Chimie de Montpellier</orgName>
          <orgName type="acronym">ENSCM</orgName>
          <date type="end">2021-12-31</date>
          <desc>
            <address>
              <addrLine>8 Rue de l'Ecole Normale 34296 Montpellier Cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.enscm.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-301088" status="VALID">
          <idno type="ROR">https://ror.org/01rk35k63</idno>
          <orgName>Université de Lyon</orgName>
          <desc>
            <address>
              <addrLine>92 rue Pasteur - CS 30122, 69361 Lyon Cedex 07</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.universite-lyon.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-219748" status="VALID">
          <idno type="IdRef">052444724</idno>
          <idno type="ISNI">0000 0001 2292 0228</idno>
          <orgName>Institut National des Sciences Appliquées de Lyon</orgName>
          <orgName type="acronym">INSA Lyon</orgName>
          <date type="start">1957-03-18</date>
          <desc>
            <address>
              <addrLine>20 Avenue Albert Einstein, 69621 Villeurbanne cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insa-lyon.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301088" type="direct"/>
            <relation active="#struct-301232" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301232" status="VALID">
          <idno type="IdRef">162105150</idno>
          <orgName>Institut National des Sciences Appliquées</orgName>
          <orgName type="acronym">INSA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>