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            <funder>This research was supported by the Sentinel North Program of University Laval, and the Natural Sciences and Engineering Research Council (NSERC). V.A.G. Rivera would like acknowledgements also to the Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq - process 174213/2023–9). This research has benefited from financial support from “Région Nouvelle Aquitaine” (project AAPR2020-2019-8193110). We acknowledge also the financial support from the CNRS IRP LuMAQ and the Grand Research Program « LIGHT » Idex University of Bordeaux, and the Graduate program « EUR Light S&amp;T » PIA3 ANR-17-EURE-0027. The infrared experiments were conducted using the SIV platform at the University of Bordeaux founded by the FEDER and the Region Aquitaine.</funder>
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                <term xml:lang="en">Dehydrating agents</term>
                <term xml:lang="en">Erbium</term>
                <term xml:lang="en">Photoluminescence</term>
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              <p>In barium gallo-germanate glasses, the extrinsic absorption losses from hydroxyl (-OH) groups are mostly due to the hygroscopic nature seen in the glass, its raw precursors and from the environment during the melting process. Their vibrations (harmonic or overtone) cause detrimental absorption bands in the infrared region which limit their use as host materials for rare-earth ions emitting in the infrared. It is therefore essential to minimize the concentration of (-OH) groups in the glass. Here, we present a dehydration method to prepare barium gallo-germanate glasses at high temperature (&gt;1500 °C) under a controlled atmosphere (Ar-filled, with 0.1 ppm O2 and 0.1 ppm H2O) with ammonium bi-fluoride (NH4F–HF) as dehydrating agent to lower (–OH)–based absorption coefficient down to 0.006 cm−1 at 3300 nm wavelength. This improvement allows a significant lengthening of the lifetimes of the electronic transition in the near infrared at 1000 nm (4I11/2 → 4I15/2) and 1537 nm (4I13/2 → 4I15/2) in the glasses with ultra-low hydroxyl content due to reduced (-OH) quenching. This work paves the way for developing efficient barium gallo-germanate solid-state laser components for sensing operation in the near and mid-infrared spectral range (1–5 μm).</p>
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