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                <term xml:lang="en">Unsaturated compounds</term>
                <term xml:lang="en">Conductive materials</term>
                <term xml:lang="en">Electronic properties</term>
                <term xml:lang="en">Entropy</term>
                <term xml:lang="en">Ions</term>
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              <p>Substitutional and orientation disorders in some of the title compounds have been characterized by simulations of the X-ray diffuse scattering pattern. It is found that in most of the cases the disorder is random but accompanied by molecular displacements (size effect). The influence of a random disorder on the 2kF charge density wave (CDW), spin Peierls (SP) and on the anion ordering (AO) instabilities is analyzed. The smoothening and even the complete suppression of the AO transition is discussed in term of random interactions and random fields acting on the Ising orientational order parameter of the anions. Random interactions are relevant in the (TMTSF)2(ReO4)1-x(ClO4)x solid solution while the effect of random fields is pertinent in the (TMDTDSF)2X series and in the [(TMTSF)1-x(TMTSF)x]2ClO4 solid solution.</p>
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