<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-04898653</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-19T06:52:43+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Structural and electronic properties of the one-dimensional organic metal bis(thiodimethylene)-tetrathiafulvalene tetracyanoquinodimethane</title>
            <author role="aut">
              <persName>
                <forename type="first">C.</forename>
                <surname>Rovira</surname>
              </persName>
              <idno type="halauthorid">111702-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">J.</forename>
                <surname>Tarrés</surname>
              </persName>
              <idno type="halauthorid">3378167-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">J.</forename>
                <surname>Llorca</surname>
              </persName>
              <idno type="halauthorid">108982-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">E.</forename>
                <surname>Molins</surname>
              </persName>
              <idno type="halauthorid">166238-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">J.</forename>
                <surname>Veciana</surname>
              </persName>
              <idno type="halauthorid">150598-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">S.</forename>
                <surname>Yang</surname>
              </persName>
              <idno type="halauthorid">609842-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">D.O.</forename>
                <surname>Cowan</surname>
              </persName>
              <idno type="halauthorid">3378168-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">C.</forename>
                <surname>Garrigou-Lagrange</surname>
              </persName>
              <idno type="halauthorid">3378169-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">J.</forename>
                <surname>Amiell</surname>
              </persName>
              <idno type="halauthorid">258755-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">P.</forename>
                <surname>Delhaes</surname>
              </persName>
              <idno type="halauthorid">129938-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">E.</forename>
                <surname>Canadell</surname>
              </persName>
              <idno type="halauthorid">123959-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">J.P.</forename>
                <surname>Pouget</surname>
              </persName>
              <email type="md5">b61d7dc23b84bdd86293e7b0242e7f38</email>
              <email type="domain">u-psud.fr</email>
              <idno type="idhal" notation="numeric">1297450</idno>
              <idno type="halauthorid" notation="string">258536-1297450</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-6244-389X</idno>
              <affiliation ref="#struct-134"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>LPS</forename>
                <surname>Gestionnaire</surname>
              </persName>
              <email type="md5">892da8601da6d870e24ca8bf3ab08ad4</email>
              <email type="domain">u-psud.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2025-01-20 10:47:08</date>
              <date type="whenModified">2025-01-22 03:18:26</date>
              <date type="whenReleased">2025-01-20 10:47:08</date>
              <date type="whenProduced">1995</date>
              <ref type="externalLink" target="https://diposit.ub.edu/dspace/bitstream/2445/10672/1/112827.pdf"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="1048593">
                <persName>
                  <forename>LPS</forename>
                  <surname>Gestionnaire</surname>
                </persName>
                <email type="md5">892da8601da6d870e24ca8bf3ab08ad4</email>
                <email type="domain">u-psud.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-04898653</idno>
            <idno type="halUri">https://hal.science/hal-04898653</idno>
            <idno type="halBibtex">rovira:hal-04898653</idno>
            <idno type="halRefHtml">&lt;i&gt;Physical Review B: Condensed Matter (1978-1997)&lt;/i&gt;, 1995, 52 (12), pp.8747-8758. &lt;a target="_blank" href="https://dx.doi.org/10.1103/PhysRevB.52.8747"&gt;&amp;#x27E8;10.1103/PhysRevB.52.8747&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Physical Review B: Condensed Matter (1978-1997), 1995, 52 (12), pp.8747-8758. &amp;#x27E8;10.1103/PhysRevB.52.8747&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-PSUD">Université Paris Sud - Paris XI</idno>
            <idno type="stamp" n="UNIV-PARIS-SACLAY">Université Paris-Saclay</idno>
            <idno type="stamp" n="UNIV-PSUD-SACLAY" corresp="UNIV-PARIS-SACLAY">Université Paris Sud pour Paris Saclay</idno>
            <idno type="stamp" n="GS-PHYSIQUE">Graduate School Physique</idno>
            <idno type="stamp" n="LPSO">Laboratoire de Physique des Solides d'Orsay</idno>
            <idno type="stamp" n="URP-LPS">Laboratoire de Psychologie Sociale : contextes et régulation</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Structural and electronic properties of the one-dimensional organic metal bis(thiodimethylene)-tetrathiafulvalene tetracyanoquinodimethane</title>
                <author role="aut">
                  <persName>
                    <forename type="first">C.</forename>
                    <surname>Rovira</surname>
                  </persName>
                  <idno type="halauthorid">111702-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">J.</forename>
                    <surname>Tarrés</surname>
                  </persName>
                  <idno type="halauthorid">3378167-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">J.</forename>
                    <surname>Llorca</surname>
                  </persName>
                  <idno type="halauthorid">108982-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">E.</forename>
                    <surname>Molins</surname>
                  </persName>
                  <idno type="halauthorid">166238-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">J.</forename>
                    <surname>Veciana</surname>
                  </persName>
                  <idno type="halauthorid">150598-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">S.</forename>
                    <surname>Yang</surname>
                  </persName>
                  <idno type="halauthorid">609842-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">D.O.</forename>
                    <surname>Cowan</surname>
                  </persName>
                  <idno type="halauthorid">3378168-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">C.</forename>
                    <surname>Garrigou-Lagrange</surname>
                  </persName>
                  <idno type="halauthorid">3378169-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">J.</forename>
                    <surname>Amiell</surname>
                  </persName>
                  <idno type="halauthorid">258755-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">P.</forename>
                    <surname>Delhaes</surname>
                  </persName>
                  <idno type="halauthorid">129938-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">E.</forename>
                    <surname>Canadell</surname>
                  </persName>
                  <idno type="halauthorid">123959-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">J.P.</forename>
                    <surname>Pouget</surname>
                  </persName>
                  <email type="md5">b61d7dc23b84bdd86293e7b0242e7f38</email>
                  <email type="domain">u-psud.fr</email>
                  <idno type="idhal" notation="numeric">1297450</idno>
                  <idno type="halauthorid" notation="string">258536-1297450</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-6244-389X</idno>
                  <affiliation ref="#struct-134"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="OLD">146144</idno>
                <idno type="issn">0163-1829</idno>
                <idno type="eissn">1095-3795</idno>
                <title level="j">Physical Review B: Condensed Matter (1978-1997)</title>
                <imprint>
                  <publisher>American Physical Society</publisher>
                  <biblScope unit="volume">52</biblScope>
                  <biblScope unit="issue">12</biblScope>
                  <biblScope unit="pp">8747-8758</biblScope>
                  <date type="datePub">1995</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1103/PhysRevB.52.8747</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="phys">Physics [physics]</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>The synthesis and structural characterization at room temperature and 130 K of the organic charge-transfer salt bis(thiodimethylene)-tetrathiafulvalene tetracyanoquinodimethane (BTDMTTF-TNCQ) is reported. X-ray diffuse scattering as well as ir and Raman measurements show that the charge transfer in this salt is ∼0.5. BTDMTTF-TCNQ remains metallic down to very low temperatures but exhibits an anomaly at 175 K in the conductivity and thermopower which could be related to some unusual structural modification of the unit cell. Band-structure calculations show that this salt is a narrow-band one-dimensional metal. The high value of the spin susceptibility, the low value of the conductivity, and the observation of a 4kF charge-density-wave (CDW) instability around room temperature prove that it is a highly correlated metal. In contrast with other salts of the TTF-TCNQ family, BTDMTTF-TCNQ does not exhibit critical 2kF structural fluctuations. It is proposed that the absence of the 2kF CDW transition is due to the stronger interlocking of the donor and acceptor molecules due to the presence of the sulfur atoms in the central position of the outer five-membered rings of the BTDMTTF donor.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-134" status="OLD">
          <orgName>Laboratoire de Physique des Solides</orgName>
          <orgName type="acronym">LPS</orgName>
          <date type="end">2019-12-31</date>
          <desc>
            <address>
              <addrLine>Bat. 510 91405 Orsay cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.lps.u-psud.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-92966" type="direct"/>
            <relation name="UMR8502" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-92966" status="OLD">
          <idno type="ROR">https://ror.org/028rypz17</idno>
          <orgName>Université Paris-Sud - Paris 11</orgName>
          <orgName type="acronym">UP11</orgName>
          <date type="end">2019-12-31</date>
          <desc>
            <address>
              <addrLine>Bâtiment 300 - 91405 Orsay cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.u-psud.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>