<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-04898581</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-22T09:02:16+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Organic-inorganic molecular aggregates and their association within long-range ordered crystalline assemblies: Relevance to the template effect in solid-state chemistry</title>
            <author role="aut">
              <persName>
                <forename type="first">Anne</forename>
                <surname>Dolbecq</surname>
              </persName>
              <idno type="halauthorid">1916-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Kamal</forename>
                <surname>Boubekeur</surname>
              </persName>
              <idno type="halauthorid">126100-0</idno>
              <affiliation ref="#struct-134"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Patrick</forename>
                <surname>Batail</surname>
              </persName>
              <idno type="halauthorid">394783-0</idno>
              <affiliation ref="#struct-134"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Enric</forename>
                <surname>Canadell</surname>
              </persName>
              <idno type="halauthorid">135595-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Pascale</forename>
                <surname>Auban-Senzier</surname>
              </persName>
              <email type="md5">23f886676f71b0aeb4c1c0f007c29721</email>
              <email type="domain">lps.u-psud.fr</email>
              <idno type="idhal" notation="string">pascale-auban-senzier</idno>
              <idno type="idhal" notation="numeric">828745</idno>
              <idno type="halauthorid" notation="string">56937-828745</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-7672-4759</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=RqppUZQAAAAJ</idno>
              <affiliation ref="#struct-1208230"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Claude</forename>
                <surname>Coulon</surname>
              </persName>
              <idno type="halauthorid">237424-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Knud</forename>
                <surname>Lerstrup</surname>
              </persName>
              <idno type="halauthorid">3378143-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Klaus</forename>
                <surname>Bechgaard</surname>
              </persName>
              <idno type="halauthorid">56230-0</idno>
            </author>
            <editor role="depositor">
              <persName>
                <forename>LPS</forename>
                <surname>Gestionnaire</surname>
              </persName>
              <email type="md5">892da8601da6d870e24ca8bf3ab08ad4</email>
              <email type="domain">u-psud.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2025-01-20 10:46:17</date>
              <date type="whenModified">2025-01-22 03:18:42</date>
              <date type="whenReleased">2025-01-20 10:46:17</date>
              <date type="whenProduced">1995</date>
              <ref type="externalLink" target="https://api.istex.fr/ark:/67375/QHD-B9T5FS96-J/fulltext.pdf?sid=hal"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="1048593">
                <persName>
                  <forename>LPS</forename>
                  <surname>Gestionnaire</surname>
                </persName>
                <email type="md5">892da8601da6d870e24ca8bf3ab08ad4</email>
                <email type="domain">u-psud.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-04898581</idno>
            <idno type="halUri">https://hal.science/hal-04898581</idno>
            <idno type="halBibtex">dolbecq:hal-04898581</idno>
            <idno type="halRefHtml">&lt;i&gt;Journal of Materials Chemistry&lt;/i&gt;, 1995, 5 (10), pp.1707-1718. &lt;a target="_blank" href="https://dx.doi.org/10.1039/JM9950501707"&gt;&amp;#x27E8;10.1039/JM9950501707&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Journal of Materials Chemistry, 1995, 5 (10), pp.1707-1718. &amp;#x27E8;10.1039/JM9950501707&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-PSUD">Université Paris Sud - Paris XI</idno>
            <idno type="stamp" n="UNIV-PARIS-SACLAY">Université Paris-Saclay</idno>
            <idno type="stamp" n="UNIV-PSUD-SACLAY" corresp="UNIV-PARIS-SACLAY">Université Paris Sud pour Paris Saclay</idno>
            <idno type="stamp" n="GS-PHYSIQUE">Graduate School Physique</idno>
            <idno type="stamp" n="LPSO">Laboratoire de Physique des Solides d'Orsay</idno>
            <idno type="stamp" n="URP-LPS">Laboratoire de Psychologie Sociale : contextes et régulation</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Organic-inorganic molecular aggregates and their association within long-range ordered crystalline assemblies: Relevance to the template effect in solid-state chemistry</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Anne</forename>
                    <surname>Dolbecq</surname>
                  </persName>
                  <idno type="halauthorid">1916-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Kamal</forename>
                    <surname>Boubekeur</surname>
                  </persName>
                  <idno type="halauthorid">126100-0</idno>
                  <affiliation ref="#struct-134"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Patrick</forename>
                    <surname>Batail</surname>
                  </persName>
                  <idno type="halauthorid">394783-0</idno>
                  <affiliation ref="#struct-134"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Enric</forename>
                    <surname>Canadell</surname>
                  </persName>
                  <idno type="halauthorid">135595-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Pascale</forename>
                    <surname>Auban-Senzier</surname>
                  </persName>
                  <email type="md5">23f886676f71b0aeb4c1c0f007c29721</email>
                  <email type="domain">lps.u-psud.fr</email>
                  <idno type="idhal" notation="string">pascale-auban-senzier</idno>
                  <idno type="idhal" notation="numeric">828745</idno>
                  <idno type="halauthorid" notation="string">56937-828745</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-7672-4759</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=RqppUZQAAAAJ</idno>
                  <affiliation ref="#struct-1208230"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Claude</forename>
                    <surname>Coulon</surname>
                  </persName>
                  <idno type="halauthorid">237424-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Knud</forename>
                    <surname>Lerstrup</surname>
                  </persName>
                  <idno type="halauthorid">3378143-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Klaus</forename>
                    <surname>Bechgaard</surname>
                  </persName>
                  <idno type="halauthorid">56230-0</idno>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">15751</idno>
                <idno type="issn">0959-9428</idno>
                <idno type="eissn">1364-5501</idno>
                <title level="j">Journal of Materials Chemistry</title>
                <imprint>
                  <publisher>Royal Society of Chemistry</publisher>
                  <biblScope unit="volume">5</biblScope>
                  <biblScope unit="issue">10</biblScope>
                  <biblScope unit="pp">1707-1718</biblScope>
                  <date type="datePub">1995</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1039/JM9950501707</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>A series of conducting radical cation salts of 1,2-bis(4,5-dimethyltetrathiafulvalen-4′-yl)ethane [bis(DMTTF)ethane], a bifunctional donor with two quasi-degenerate redox functionalities, has been prepared by electrocrystallization; two kinds of binary radical cation salts, [bis(DMTTF)ethane]3[Re6Q6Cl8], Q = Se, 1; S, 2 and [bis(DMTTF)ethane]2[Re6Q5Cl9], Q = Se, 3; S, 4 and a ternary phase [bis(DMTTF)ethane]5[Re6Se6Cl 8][Re6Se5Cl9], 5, have been obtained. All five compounds present the same one-dimensional (1D) structural organization in which a stack of donor molecules is surrounded by cluster anions. The degree of oligomerization of the radical cation moieties within the stack is shown to be controlled solely by the cluster anion charge. Thus, the long-range ordered merging of 1 and 3 has led to the formation of the molecular alloy 5. The electronic properties of 1-5 deduced from the band structure calculations and the magnetic properties observed by single-crystal EPR are analysed in relation with the structural changes and the spin distribution on the TTF moieties. The role of the organic chalcogen-inorganic chalcogen interactions is also discussed. In particular, the spin-Peierls transition observed in 1 and absent in 2 is shown to be associated with significant donor-anion interactions only present in 1. Finally, the relation between the degree of purity of 1 and the absence of a pseudo-gap in the spin-Peierls transition is demonstrated.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-134" status="OLD">
          <orgName>Laboratoire de Physique des Solides</orgName>
          <orgName type="acronym">LPS</orgName>
          <date type="end">2019-12-31</date>
          <desc>
            <address>
              <addrLine>Bat. 510 91405 Orsay cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.lps.u-psud.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-92966" type="direct"/>
            <relation name="UMR8502" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="researchteam" xml:id="struct-1208230" status="OLD">
          <orgName>Laboratoire de Physique des Solides - HP</orgName>
          <orgName type="acronym">LPS</orgName>
          <date type="end">2019-12-31</date>
          <desc>
            <address>
              <addrLine>Bat. 510 91405 Orsay cedex</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-134" type="direct"/>
            <relation active="#struct-92966" type="indirect"/>
            <relation name="UMR8502" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-92966" status="OLD">
          <idno type="ROR">https://ror.org/028rypz17</idno>
          <orgName>Université Paris-Sud - Paris 11</orgName>
          <orgName type="acronym">UP11</orgName>
          <date type="end">2019-12-31</date>
          <desc>
            <address>
              <addrLine>Bâtiment 300 - 91405 Orsay cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.u-psud.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>