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            <title xml:lang="en">Rational design of three-dimensional (3D) optically active molecule-based magnets</title>
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                <forename type="first">R.</forename>
                <surname>Andrés</surname>
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            <idno type="halRefHtml">&lt;i&gt;Inorganic Chemistry&lt;/i&gt;, 2001, 40 (18), pp.4633-4640. &lt;a target="_blank" href="https://dx.doi.org/10.1021/ic010363f"&gt;&amp;#x27E8;10.1021/ic010363f&amp;#x27E9;&lt;/a&gt;</idno>
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            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-PSUD">Université Paris Sud - Paris XI</idno>
            <idno type="stamp" n="UNIV-PARIS-SACLAY">Université Paris-Saclay</idno>
            <idno type="stamp" n="UNIV-PSUD-SACLAY" corresp="UNIV-PARIS-SACLAY">Université Paris Sud pour Paris Saclay</idno>
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                <title xml:lang="en">Rational design of three-dimensional (3D) optically active molecule-based magnets</title>
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                    <forename type="first">R.</forename>
                    <surname>Andrés</surname>
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                    <surname>Brissard</surname>
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                    <surname>Gruselle</surname>
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                    <surname>Train</surname>
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                    <forename type="first">J.</forename>
                    <surname>Vaissermann</surname>
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                    <forename type="first">B.</forename>
                    <surname>Malézieux</surname>
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                    <forename type="first">J.-P.</forename>
                    <surname>Jamet</surname>
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                    <forename type="first">M.</forename>
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                <title level="j">Inorganic Chemistry</title>
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                  <publisher>American Chemical Society</publisher>
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                <term xml:lang="en">X ray diffraction</term>
                <term xml:lang="en">bipyridine derivative</term>
                <term xml:lang="en">phenylpyridine derivative</term>
                <term xml:lang="en">pyridine derivative</term>
                <term xml:lang="en">ruthenium derivative</term>
                <term xml:lang="en">unclassified drug</term>
                <term xml:lang="en">article</term>
                <term xml:lang="en">chemical bond</term>
                <term xml:lang="en">chemical reaction</term>
                <term xml:lang="en">synthesis</term>
                <term xml:lang="en">structure analysis</term>
                <term xml:lang="en">structure activity relation</term>
                <term xml:lang="en">reaction analysis</term>
                <term xml:lang="en">optics</term>
                <term xml:lang="en">magnet</term>
                <term xml:lang="en">low temperature</term>
                <term xml:lang="en">enantiomer</term>
                <term xml:lang="en">circular dichroism</term>
                <term xml:lang="en">chemical structure</term>
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              <p>To elucidate the relation between structural and magnetic properties, we have synthesized molecular materials having both Cotton effects and a ferromagnetic long range order. Such optically active 3D molecule-based magnets were rationally designed using the enantioselective template effect of optically active cations, namely Δ or Λ [Ru(bpy)3, ClO4]+ or Δ or Λ [Ru(bpy)3ppy]+ (bpy = bipyridine; ppy = phenylpyridine). Such cations are able to template the formation of optically active 3D anionic networks in which transition metal ions (Cr-Mn) and (Cr-Ni) are connected by oxalate ligands (ox). Following this strategy, we described the synthesis of {[Ru-(bpy)3]2+, ClO4-, [MnIICrIII(ox)3]-}n and {[Ru(bpy)2ppy]+, [MIICrIII(ox)3]-}n with MII = MnII, NiII in their optically active forms. In these 3D networks, all of the metallic centers have the same configuration, Δ or Λ, as the template cation. We have determined the structure of {[ΔRu(bpy)3][ClO4][ΔMnΔCr(ox) 3]}n and {[ΛRu(bpy)2ppy]+, [ΛMnIIΛCrIII(ox)3] -}n by X-ray diffraction studies. These optically active networks show the Cotton effect and long-range ferromagnetic order at low temperatures. The magnetic circular dichroism of {[Ru(bpy)3]2+, ClO4-, [MnIICrIII(ox)3]-}n at 2 K is reported.</p>
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