Article Dans Une Revue Dalton Transactions Année : 2025

Of perfluorinated aryllead(II) complexes

Résumé

The pentafluorophenyl moiety C6F5− was succesfully employed for the first time in lead(II) chemistry. We are reporting on the stable and soluble organolead(II) polymer [Pb(C6F5)2(dx)]∞ (dx = dioxane). An example of a Pb(II) “ate” complex paired with a trimetallic magnesium cation is also presented. Our foray into related tin(II) chemistry shows that this behaviour cannot be extended to the lighter tetrel, and is specific to lead(II).

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hal-04867085 , version 1 (06-01-2025)

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Adrian-Alexandru Someşan, Thierry Roisnel, Yann Sarazin. Of perfluorinated aryllead(II) complexes. Dalton Transactions, 2025, 54, pp.482-486. ⟨10.1039/d4dt03167a⟩. ⟨hal-04867085⟩
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