Article Dans Une Revue Journal of Inclusion Phenomena and Macrocyclic Chemistry Année : 2025

Synthesis and organocatalytical evaluation of optically pure inherently chiral calix[4]arene phosphoric acids

Résumé

Two pairs of diastereomerically pure calix[4]arene phosphoric acid derivatives with ABHH and ABCH substitution patterns were synthesized via phosphorylation and phosphotropic rearrangement on the narrow rim. These new cone-shaped, inherently chiral calixarenes were tested as organocatalysts in the stereoselective aza-Diels–Alder reaction of imines with Danishefsky's diene, as well as in the stereoselective epoxide ring opening.

Fichier principal
Vignette du fichier
Karpus, Synthesis and organocatalytical evaluation, 2024.pdf (649.41 Ko) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)
Licence

Dates et versions

hal-04829067 , version 1 (11-12-2024)

Licence

Identifiants

Citer

Andrii Karpus, Oleksandr Yesypenko, Jean-Claude Daran, Zoia Voitenko, Eric Manoury, et al.. Synthesis and organocatalytical evaluation of optically pure inherently chiral calix[4]arene phosphoric acids. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2025, 105, pp.75-86. ⟨10.1007/s10847-024-01267-9⟩. ⟨hal-04829067⟩
111 Consultations
101 Téléchargements

Altmetric

Partager

  • More