Role of Cationic Organization on Water Dynamics in Saponite Clays - Archive ouverte HAL
Article Dans Une Revue Journal of Physical Chemistry C Année : 2024

Role of Cationic Organization on Water Dynamics in Saponite Clays

Résumé

Water dynamics impacts many phenomena from geosciences to biology, especiallly in confined environments. In the presence of charged interfaces, there are some ions the role of which with regards to the water dynamics is unclear. Here a synthetic saponite clay, which is oriented in a film, is used as confining medium in the bilayer state. It confines two water layers between negatively charged planes, the charge of which is compensated by sodium cations. Water dynamics is determined both parallel and perpendicular to the charged clay layers with Neutron Spin Echo (NSE). This technique gives access to long enough times and directly provides the intermediate 1 scattering function that is calculated on the other hand by Molecular Dynamics (MD) simulations. These latter also enable the study of cations dynamics, not experimentally accessible on this time scale. The results point towards a huge role of these cations on the water dynamics, mainly through their local structure and localization between the charged confining planes.
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Dates et versions

hal-04783879 , version 1 (14-11-2024)

Identifiants

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Virginie Marry, Sébastien Le Crom, Eric Ferrage, Laurent Michot, Bela Farago, et al.. Role of Cationic Organization on Water Dynamics in Saponite Clays. Journal of Physical Chemistry C, 2024, 128 (10), pp.4233-4244. ⟨10.1021/acs.jpcc.3c05150⟩. ⟨hal-04783879⟩
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