Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides
Résumé
The synthesis of actinide tetrarhenate complexes completes a series of iridate, osmate, and rhenate polyhydrides, allowing for structural and bonding comparisons to be made. Computational studies examine the bonding interactions, particularly between metals, in these complexes. Several factors -including metal oxidation state, coordination number, and dispersion effects -affect metalmetal distances and covalency in these actinide tetrametallates. Related osmium and rhenium octametallic U2M6 clusters are synthesized and described, and subjected to similar structural and electronic analyses.
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