Article Dans Une Revue Inorganic Chemistry Année : 2024

Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides

Résumé

The synthesis of actinide tetrarhenate complexes completes a series of iridate, osmate, and rhenate polyhydrides, allowing for structural and bonding comparisons to be made. Computational studies examine the bonding interactions, particularly between metals, in these complexes. Several factors -including metal oxidation state, coordination number, and dispersion effects -affect metalmetal distances and covalency in these actinide tetrametallates. Related osmium and rhenium octametallic U2M6 clusters are synthesized and described, and subjected to similar structural and electronic analyses.

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hal-04749940 , version 1 (23-10-2024)

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Christopher Ye, Iker del Rosal, Sheridon Kelly, Erik Ouellette, Laurent Maron, et al.. Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides. Inorganic Chemistry, inPress, ⟨10.1021/acs.inorgchem.4c03449⟩. ⟨hal-04749940⟩
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