Resonant Auger decay of iodobenzene below the I 4d edge - Archive ouverte HAL
Article Dans Une Revue The Journal of Chemical Physics Année : 2024

Resonant Auger decay of iodobenzene below the I 4d edge

Résumé

New data are presented on the resonant Auger decay of iodobenzene (C6H5I) in the region of the I 4d−1 ionization threshold. The excited molecules decay by participator and spectator processes to populate single-hole valence states and two-hole, one-particle excited states of the cation, providing new information on the structure of C6H5I+. Excitation of dissociative C6H5I (I 4d5/2,3/2−1)σ* resonances can, in principle, result in ultrafast dissociation to C6H5 + I** and the subsequent autoionization of I**, but no evidence for this process is observed. The results are compared with our recent study of the resonant Auger decay of methyl iodide (CH3I).
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hal-04749344 , version 1 (23-10-2024)

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Stephen T Pratt, Ugo Jacovella, Bérenger Gans, John D Bozek, David M P Holland. Resonant Auger decay of iodobenzene below the I 4d edge. The Journal of Chemical Physics, 2024, 160 (17), pp.174309. ⟨10.1063/5.0203661⟩. ⟨hal-04749344⟩
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